In situ ligands syntheses involving malic acid in hydrothermal condition

被引：24

作者：

Lu, Jing

Chu, De-Qing

Yu, Jie-Hui

Zhang, Xiao

Bi, Ming-Hui

Xu, Ji-Qing ^{[1
]}

Yu, Xiao-Yang

Yang, Qing-Feng

机构：

[1] Jilin Univ, Coll Chem, Changchun 130023, Jilin, Peoples R China

[2] Jilin Univ, State Key Lab Inorgan Synth, Changchun 130023, Jilin, Peoples R China

[3] Jilin Univ, Preparat Dept Chem, Changchun 130023, Jilin, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 08期

关键词：

in situ ligand synthesis; malic acid; metal nature; hydrothermal condition;

D O I：

10.1016/j.ica.2006.02.043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three kinds of in situ ligands syntheses involving malic acid, i.e. hydration, intra-molecular dehydration and isomeric transformation, have been found during studying on the syntheses of compounds 1-5. According these results, it can be concluded that the nature of metal atom affects strongly the in situ ligand synthesis, vice versa; the in situ ligand synthesis is favorable to the formation of coordination compound. (c) 2006 Elsevier B.V. All rights reserved.

引用

收藏

页码：2495 / 2500

页数：6

相关论文

共 30 条

[1] A 3-D noninterpenetrating diamondoid network of a decanuclear copper(I) complex [J].

Cheng, JK ;

Chen, YB ;

Wu, L ;

Zhang, J ;

Wen, YH ;

Li, ZJ ;

Yao, YG .

INORGANIC CHEMISTRY, 2005, 44 (10) :3386-3388

[2] Mononuclear and mixed-valence binuclear oxovanadium complexes with benzimidazole-derived chelating agents [J].

Ghosh, S ;

Nanda, KK ;

Addison, AW ;

Butcher, RJ .

INORGANIC CHEMISTRY, 2002, 41 (08) :2243-2249

[3] Hydrothermal synthesis, crystal structures of two new transition metal coordination chain polymers with mixed ligands [J].

He, X ;

Lu, CZ ;

Yan, Y .

INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (07) :851-853

[4] A new route for preparing coordination polymers from hydrothermal reactions involving in situ ligand synthesis [J].

Hu, XX ;

Xu, JQ ;

Cheng, P ;

Chen, XY ;

Cui, XB ;

Song, JF ;

Yang, GD ;

Wang, TG .

INORGANIC CHEMISTRY, 2004, 43 (07) :2261-2266

[5] A mixed-ligand coordination polymer from the in situ, Cu(I)-mediated isomerization of bis(4-pyridyl)ethylene [J].

Knaust, JM ;

Keller, SW .

INORGANIC CHEMISTRY, 2002, 41 (22) :5650-5652

[6] Twelve-connected net with face-centered cubic topology:: A coordination polymer based on [Cu12(μ4-SCH3)6]6+ clusters and CN- linkers [J].

Li, D ;

Wu, T ;

Zhou, XP ;

Zhou, R ;

Hitang, XC .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (27) :4175-4178

[7] Transformation of inorganic sulfur into organic sulfur: A novel photoluminescent 3-D polymeric complex involving ligands in situ formation [J].

Li, D ;

Wu, T .

INORGANIC CHEMISTRY, 2005, 44 (05) :1175-1177

[8] A novel octupolar metal-organic NLO material based on a chiral 2D coordination network [J].

Lin, WB ;

Wang, ZY ;

Ma, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (48) :11249-11250

[9] Dehydrogenative coupling of phenanthroline under hydrothermal conditions:: crystal structure of a novel layered vanadate complex constructed of 4,8,10-net sheets:: [(2,2′-biphen)Co]V3O8.5 [J].

Liu, CM ;

Gao, S ;

Kou, HZ .

CHEMICAL COMMUNICATIONS, 2001, (17) :1670-1671

[10] Synthesis, characterization and novel crystal structure of (salicylaldehyde-4-phenylthiosemicarbazidato) ammonium dioxovanadate(V) with a V-S bond [J].

Milanesio, M ;

Viterbo, D ;

Hernández, RP ;

Rodríguez, JD ;

Ramírez-Ortiz, J ;

Valdés-Martínez, J .

INORGANICA CHIMICA ACTA, 2000, 306 (01) :125-129