Synthesis of tetraamino derivative of thiacalix[4]arene and its acid-base property studied by UV spectroscopy

被引:20
作者
Hu, XJ
Xia, N
Ye, F
Ren, J
Shi, XF
机构
[1] Tongji Univ, Dept Chem, Shanghai 200092, Peoples R China
[2] Tongji Univ, Sch Mat Sci, Shanghai 200092, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
关键词
thiacalixarene; acid-base property;
D O I
10.1016/j.saa.2003.07.007
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The tetraamino derivative of thiacalix[4]arene (4) was synthesized and characterized. Its acid-base property in water solution was studied by UV spectroscopy. The pH distribution regions of several acidic or basic species of 4 were determined. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:1427 / 1430
页数:4
相关论文
共 9 条
[1]   Synthesis and solid state structural analysis of 1,3-alternate conformer of tetrathiacalix[4]arene tetra-ester, -acid and -ether derivatives [J].
Akdas, H ;
Jaunky, W ;
Graf, E ;
Hosseini, MW ;
Planeix, JM ;
De Cian, A ;
Fischer, J .
TETRAHEDRON LETTERS, 2000, 41 (19) :3601-3606
[2]  
GUSTCHE CD, 1998, CALIXARENES REVISITE
[3]   Selective synthesis of three conformational isomers of tetrakis[(ethoxycarbonyl)methoxy]thiacalix[4]arene and their complexation properties towards alkali metal ions [J].
Iki, N ;
Narumi, F ;
Fujimoto, T ;
Morohashi, N ;
Miyano, S .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1998, (12) :2745-2750
[4]   Novel molecular receptors based on a thiacalix[4]arene platform. Preparations of the di- and tetracarboxylic acid derivatives and their binding properties towards transition metal ions [J].
Iki, N ;
Morohashi, N ;
Narumi, F ;
Fujimoto, T ;
Suzuki, T ;
Miyano, S .
TETRAHEDRON LETTERS, 1999, 40 (41) :7337-7341
[5]   Calix[4]arenes comprised of aniline units [J].
Katagiri, H ;
Iki, N ;
Hattori, T ;
Kabuto, C ;
Miyano, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (04) :779-780
[6]   Facile synthesis of p-tert-butylthiacalix[4]arene by the reaction of p-tert-butylphenol with elemental sulfur in the presence of a base [J].
Kumagai, H ;
Hasegawa, M ;
Miyanari, S ;
Sugawa, Y ;
Sato, Y ;
Hori, T ;
Ueda, S ;
Kamiyama, H ;
Miyano, S .
TETRAHEDRON LETTERS, 1997, 38 (22) :3971-3972
[7]   Tetraalkylated 2,8,14,20-tetrathiacalix [4] arenes:: Novel infinite channels in the solid state [J].
Lhoták, P ;
Himl, M ;
Pakhomova, S ;
Stibor, I .
TETRAHEDRON LETTERS, 1998, 39 (48) :8915-8918
[8]   Nitration of thiacalix[4]arene derivatives [J].
Lhoták, P ;
Svoboda, J ;
Stibor, I ;
Sykora, J .
TETRAHEDRON LETTERS, 2002, 43 (41) :7413-7417
[9]   Synthesis and properties of new thiacalixarene derivatives with palladium ion [J].
Ye, ZF ;
Pan, ZG ;
He, WJ ;
Shi, XF ;
Zhu, LG .
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2001, 40 (1-2) :89-93