Multifunctional, multilayer, multiscale:: Integrative synthesis of complex macroporous and mesoporous thin films with spatial separation of porosity and function

被引:74
作者
Angelome, Paula C. [1 ]
Fuertes, M. Cecilia [1 ]
Soler-Illia, Galo J. A. A. [1 ]
机构
[1] Comis Nacl Energma Atom, Ctr Atom Constituyentes, Unidad Activ Quim, Buenos Aires, DF, Argentina
关键词
D O I
10.1002/adma.200600439
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Complex multilayered thin-film architectures are fabricated by sequentially stacking mesoporous and macroporous layers with varying structure and properties. A series of deposition-stabilization steps are used to sequentially deposit the component layers of the films in order to obtain interconnected systems with a precise ordering of accessible cavities, as shown in the figure.
引用
收藏
页码:2397 / +
页数:7
相关论文
共 45 条
[31]   Pore Structure Control of Silica Gels Based on Phase Separation [J].
Nakanishi, Kazuki .
JOURNAL OF POROUS MATERIALS, 1997, 4 (02) :67-112
[32]   Mesostructured hybrid organic-inorganic thin films [J].
Nicole, L ;
Boissière, C ;
Grosso, D ;
Quach, A ;
Sanchez, C .
JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (35-36) :3598-3627
[33]   Advanced selective optical sensors based on periodically organized mesoporous hybrid silica thin films [J].
Nicole, L ;
Boissière, C ;
Grosso, D ;
Hesemann, P ;
Moreau, J ;
Sanchez, C .
CHEMICAL COMMUNICATIONS, 2004, (20) :2312-2313
[34]   Functionalized mesoporous hybrid thin films as selective membranes [J].
Otal, EH ;
Angelomé, PC ;
Bilmes, SA ;
Soler-Illia, GJAA .
ADVANCED MATERIALS, 2006, 18 (07) :934-+
[35]   Growth of gold nanoparticle arrays in TiO2 mesoporous matrixes [J].
Pérez, MD ;
Otal, E ;
Bilmes, SA ;
Soler-Illia, GJAA ;
Crepaldi, EL ;
Grosso, D ;
Sanchez, C .
LANGMUIR, 2004, 20 (16) :6879-6886
[36]   Mesoporous hybrid thin films: The physics and chemistry beneath [J].
Soler-Illia, G. J. A. A. ;
Innocenzi, P. .
CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (17) :4478-4494
[37]   Highly ordered hybrid mesoporous bifunctional thin films [J].
Soler-Illia, GJAA ;
Angelomé, PC ;
Bozzano, P .
CHEMICAL COMMUNICATIONS, 2004, (24) :2854-2855
[38]   Structural control in self-standing mesostructured silica oriented membranes and xerogels [J].
Soler-Illia, GJAA ;
Crepaldi, EL ;
Grosso, D ;
Durand, D ;
Sanchez, C .
CHEMICAL COMMUNICATIONS, 2002, (20) :2298-2299
[39]   Chemical strategies to design textured materials: From microporous and mesoporous oxides to nanonetworks and hierarchical structures [J].
Soler-illia, GJD ;
Sanchez, C ;
Lebeau, B ;
Patarin, J .
CHEMICAL REVIEWS, 2002, 102 (11) :4093-4138
[40]   Block copolymer-templated mesoporous oxides [J].
Soler-Illia, GJDA ;
Crepaldi, EL ;
Grosso, D ;
Sanchez, C .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2003, 8 (01) :109-126