Crystallographic analysis of high quality poly-Si thin films deposited by atmospheric pressure chemical vapor deposition

被引:7
作者
Ishikawa, Y [1 ]
Yamamoto, Y [1 ]
Hatayama, T [1 ]
Uraoka, Y [1 ]
Fuyuki, T [1 ]
机构
[1] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300101, Japan
关键词
polycrystalline silicon; thin film solar cell; chemical vapor deposition; dichlorosilane; crystallinity;
D O I
10.1016/S0927-0248(02)00081-8
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Crystallinity of thin film polycrystalline silicon (poly-Si) grown by atmospheric pressure chemical vapor deposition has been investigated by X-ray diffraction measurement and Raman spectroscopy. Poly-Si films deposited at high temperatures of 850-1050degreesC preferred to <220> direction. By Raman spectroscopy, the broad peak of around 480-500 cm(-1) belonged to microcrystalline Si (muc-Si) phase was observed even for the poly-Si deposited at 950degreesC. After high-temperature annealing (1050degreesC) <331> direction of poly-Si increased. This result indicates that the pc-Si phase at grain boundary became poly-Si phase preferred to <331> direction by high-temperature annealing. Effective diffusion length of poly-Si films deposited at 1000degreesC was estimated to be 11.9-13.5 mum and 10.2-12.9 mum before and after annealing, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:255 / 260
页数:6
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