Control of conductivity type in undoped ZnO thin films grown by metalorganic vapor phase epitaxy

The properties of the ZnO thin films prepared by metalorganic vapor phase epitaxy under various oxygen partial pressures were thoroughly studied. It was found that the conduction type in undoped ZnO epilayers could be controlled by adjusting the family VI precursor, oxygen partial pressure during growth. The films were characteristic of n-type conductivity under oxygen partial pressure lower than 45 Pa. With the increase of oxygen content, the crystallinity of the ZnO thin films was degraded to polycrystalline with additional (10-12) orientation and the intrinsic p-type ZnO was produced as the oxygen partial pressure was larger than 55 Pa. The hole concentration and mobility could reach to 1.59x10(16) cm(-3) and 9.23 cm2 V-1 s-1, and the resistivity was 42.7 Omega cm. The near-band-edge emission and the deep level emission in photoluminescence (PL) spectra at room temperature were influenced strongly by the oxygen partial pressure. Temperature-dependent PL spectra in n-type ZnO films showed a dominant neutral-donor bound exciton emission, while p-ZnO was dominated by neutral-acceptor bound exciton emission. Both peaks increased in intensity with the decrease of the temperature and shifted to the short-wavelength side. The band that originated from zinc vacancies emerged at a temperature lower than 155 K only in the p-type films. The origin of intrinsic p-type conductivity in ZnO thin films might be related to zinc vacancy. (C) 2004 American Institute of Physics.