Nitrogen-doped p-type ZnO layers prepared with H2O vapor-assisted metalorganic molecular-beam epitaxy

被引:125
作者
Ashrafi, ABMA [1 ]
Suemune, I [1 ]
Kumano, H [1 ]
Tanaka, S [1 ]
机构
[1] Hokkaido Univ, Res Inst Elect Sci, Optoelect Labs, Sapporo, Hokkaido 0600812, Japan
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS | 2002年 / 41卷 / 11B期
关键词
H2O vapor; undoped ZnO; N doped p-ZnO; H passivation; neutral acceptor-bound exciton;
D O I
10.1143/JJAP.41.L1281
中图分类号
O59 [应用物理学];
学科分类号
摘要
Nitrogen (N) doping in ZnO is studied to realize reproducible p-type conductivity. Undoped ZnO layers prepared on a-face of sapphire substrates with H2O vapor-assisted growth showed n-type conductivity. However, N-doped ZnO (ZnO:N) layers grown in the similar manner showed the type conversion to p-type conductivity. As-grown p-type ZnO:N layers showed low net acceptor concentrations (N-A-N-D) of similar to10(14) cm(-3), but thermal annealing of the N-doped ZnO samples as well as the optimization of growth parameters increased the N-A-N-D up to similar to5 x 10(16) cm(-3). Photoluminescence measurements showed consistent spectra with the electrical properties by a clear conversion from neutral donor-bound exciton emission in n-ZnO to neutral acceptor-bound exciton emission in the p-ZnO layers.
引用
收藏
页码:L1281 / L1284
页数:4
相关论文
共 12 条
[1]   ZnO diode fabricated by excimer-laser doping [J].
Aoki, T ;
Hatanaka, Y ;
Look, DC .
APPLIED PHYSICS LETTERS, 2000, 76 (22) :3257-3258
[2]   H2O-vapor-activated ZnO growth on a-face sapphire substrates by metalorganic molecular-beam epitaxy [J].
Ashrafi, ABMA ;
Suemune, I ;
Kumano, H .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2002, 41 (5A) :2851-2854
[3]   Growth and characterization of hypothetical zinc-blende ZnO films on GaAs(001) substrates with ZnS buffer layers [J].
Ashrafi, ABMA ;
Ueta, A ;
Avramescu, A ;
Kumano, H ;
Suemune, I ;
Ok, YW ;
Seong, TY .
APPLIED PHYSICS LETTERS, 2000, 76 (05) :550-552
[4]   Characterization of homoepitaxial p-type ZnO grown by molecular beam epitaxy [J].
Look, DC ;
Reynolds, DC ;
Litton, CW ;
Jones, RL ;
Eason, DB ;
Cantwell, G .
APPLIED PHYSICS LETTERS, 2002, 81 (10) :1830-1832
[5]   Growth of p-type zinc oxide films by chemical vapor deposition [J].
Minegishi, K ;
Koiwai, Y ;
Kikuchi, Y ;
Yano, K ;
Kasuga, M ;
Shimizu, A .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1997, 36 (11A) :L1453-L1455
[6]   Interactions between gallium and nitrogen dopants in ZnO films grown by radical-source molecular-beam epitaxy [J].
Nakahara, K ;
Takasu, H ;
Fons, P ;
Yamada, A ;
Iwata, K ;
Matsubara, K ;
Hunger, R ;
Niki, S .
APPLIED PHYSICS LETTERS, 2001, 79 (25) :4139-4141
[7]  
STRASSBURG M, 2002, 26 ICPS 2002, P45
[8]   Stimulated emission induced by exciton-exciton scattering in ZnO/ZnMgO multiquantum wells up to room temperature [J].
Sun, HD ;
Makino, T ;
Tuan, NT ;
Segawa, Y ;
Tang, ZK ;
Wong, GKL ;
Kawasaki, M ;
Ohtomo, A ;
Tamura, K ;
Koinuma, H .
APPLIED PHYSICS LETTERS, 2000, 77 (26) :4250-4252
[9]  
SZE SM, 1981, PHYSICS SEMICONDUCTO
[10]   Systematic examination of carrier polarity in composition spread ZnO thin films codoped with Ga and N [J].
Tsukazaki, A ;
Saito, H ;
Tamura, K ;
Ohtani, M ;
Koinuma, H ;
Sumiya, M ;
Fuke, S ;
Fukumura, T ;
Kawasaki, M .
APPLIED PHYSICS LETTERS, 2002, 81 (02) :235-237