Platinum-catalyzed intramolecular asymmetric hydroarylation of unactivated alkenes with indoles

被引：128

作者：

Han, Xiaoqing ^{[1
]}

Widenhoefer, Ross A. ^{[1
]}

机构：

[1] Duke Univ, PM Gross Chem Lab, Durham, NC 27708 USA

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 17期

关键词：

D O I：

10.1021/ol061441b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A 1: 1 mixture of the platinum bis(phosphine) complex [(S)-4]PtCl2[(S)-4 = (S)-3,5-t-Bu-4-MeO-MeOBIPHEP] catalyzes the intramolecular asymmetric hydroarylation of 2-(4-pentenyl) indoles in moderate to good yield with up to 90% ee.

引用

页码：3801 / 3804

页数：4

共 44 条

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