An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes

被引:865
作者
Liu, Yayuan [1 ]
Lin, Dingchang [1 ]
Yuen, Pak Yan [2 ]
Liu, Kai [1 ]
Xie, Jin [1 ]
Dauskardt, Reinhold H. [1 ]
Cui, Yi [1 ,3 ]
机构
[1] Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA
[2] Stanford Univ, Dept Mech Engn, Stanford, CA 94305 USA
[3] SLAC Natl Accelerator Lab, Stanford Inst Mat & Energy Sci, 2575 Sand Hill Rd, Menlo Pk, CA 94025 USA
关键词
COMPOSITE PROTECTIVE LAYER; ELECTROCHEMICAL-BEHAVIOR; BATTERIES; MATRIX;
D O I
10.1002/adma.201605531
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An artificial solid electrolyte interphase (SEI) is demonstrated for the efficient and safe operation of a lithium metal anode. Composed of lithium-ion-conducting inorganic nanoparticles within a flexible polymer binder matrix, the rationally designed artificial SEI not only mechanically suppresses lithium dendrite formation but also promotes homogeneous lithium-ion flux, significantly enhancing the efficiency and cycle life of the lithium metal anode.
引用
收藏
页数:8
相关论文
共 39 条
[1]   IONIC-CONDUCTIVITY IN LI3N SINGLE-CRYSTALS [J].
ALPEN, UV ;
RABENAU, A ;
TALAT, GH .
APPLIED PHYSICS LETTERS, 1977, 30 (12) :621-623
[2]   A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions [J].
Aurbach, D ;
Zinigrad, E ;
Cohen, Y ;
Teller, H .
SOLID STATE IONICS, 2002, 148 (3-4) :405-416
[3]  
AURBACH D, 1990, ELECTROCHIM ACTA, V35, P625, DOI 10.1016/0013-4686(90)87055-7
[4]   Mechanical characterization of nano-reinforced silica based sol-gel hybrid coatings on AISI 316L stainless steel using nanoindentation techniques [J].
Ballarre, Josefina ;
Jimenez-Pique, Emilio ;
Anglada, Marc ;
Pellice, Sergio A. ;
Cavalieri, Ana L. .
SURFACE & COATINGS TECHNOLOGY, 2009, 203 (20-21) :3325-3331
[5]   Lithium surface protection by polyacetylene in situ polymerization [J].
Belov, D. G. ;
Yarmolenko, O. V. ;
Peng, A. ;
Efimov, O. N. .
SYNTHETIC METALS, 2006, 156 (9-10) :745-751
[6]  
Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/nmat3191, 10.1038/NMAT3191]
[7]   Mechanical properties of biocompatible protein polymer thin films [J].
Buchko, CJ ;
Slattery, MJ ;
Kozloff, KM ;
Martin, DC .
JOURNAL OF MATERIALS RESEARCH, 2000, 15 (01) :231-242
[8]   Effect of the Anion Activity on the Stability of Li Metal Anodes in Lithium-Sulfur Batteries [J].
Cao, Ruiguo ;
Chen, Junzheng ;
Han, Kee Sung ;
Xu, Wu ;
Mei, Donghai ;
Bhattacharya, Priyanka ;
Engelhard, Mark H. ;
Mueller, Karl T. ;
Liu, Jun ;
Zhang, Ji-Guang .
ADVANCED FUNCTIONAL MATERIALS, 2016, 26 (18) :3059-3066
[9]   A Review of Solid Electrolyte Interphases on Lithium Metal Anode [J].
Cheng, Xin-Bing ;
Zhang, Rui ;
Zhao, Chen-Zi ;
Wei, Fei ;
Zhang, Ji-Guang ;
Zhang, Qiang .
ADVANCED SCIENCE, 2016, 3 (03)
[10]   Dendrite-Free Nanostructured Anode: Entrapment of Lithium in a 3D Fibrous Matrix for Ultra-Stable Lithium-Sulfur Batteries [J].
Cheng, Xin-Bing ;
Peng, Hong-Jie ;
Huang, Jia-Qi ;
Wei, Fei ;
Zhang, Qiang .
SMALL, 2014, 10 (21) :4257-4263