Dioxygen chemistry of nickel(II) dioxopentaazamacrocyclic complexes: Substituent and medium effects

被引：23

作者：

Cheng, CC ^{[1
]}

Gulia, J ^{[1
]}

Rokita, SE ^{[1
]}

Burrows, CJ ^{[1
]}

机构：

[1] SUNY STONY BROOK,DEPT CHEM,STONY BROOK,NY 11794

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 113卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

autoxidation; dioxygen; DNA; macrocycle; nickel;

D O I：

10.1016/S1381-1169(96)00215-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nickel(II) complexes of certain dioxopentaazamacrocycles are known to react with dioxygen, but the reaction is highly ligand dependent, includes an induction period, and appears to require ligand oxidation concomitant with O-2 uptake.

引用

页码：379 / 391

页数：13

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