Passivation mechanism analysis of sulfur-passivated InGaP surfaces using x-ray photoelectron spectroscopy

被引:24
作者
Tsai, CD [1 ]
Lee, CT [1 ]
机构
[1] Natl Cent Univ, Inst Opt Sci, Chungli, Taiwan
关键词
D O I
10.1063/1.373057
中图分类号
O59 [应用物理学];
学科分类号
摘要
We present the passivation mechanism and the chemistry of an (NH4)(2)S-x treated (100) InGaP surface using x-ray photoelectron spectroscopy. The native oxide on the as-etched InGaP surface could be further removed by a suitable (NH4)(2)S-x-treatment process. The measured x-ray photoelectron spectra revealed that the S atoms, in addition to bonding to the elemental sulfur, also bonded with the In and Ga atoms on the (NH4)(2)S-x-treated InGaP surface. However, the S atoms occupied the phosphorous-related vacancies instead of bonding with the P atoms. A proposed structural model of a sulfur-passivated surface is then presented. (C) 2000 American Institute of Physics. [S0021-8979(00)02209-X].
引用
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页码:4230 / 4233
页数:4
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