In situ environmental transmission electron microscopy study of oxidation of two-dimensional Ti3C2 and formation of carbon-supported TiO2

被引:311
作者
Ghassemi, H. [1 ]
Harlow, W. [1 ]
Mashtalir, O. [1 ]
Beidaghi, M. [1 ]
Lukatskaya, M. R. [1 ]
Gogotsi, Y. [1 ]
Taheri, M. L. [1 ]
机构
[1] Drexel Univ, Dept Mat Sci & Engn, AJ Drexel Nanomat Inst, Philadelphia, PA 19104 USA
基金
美国国家科学基金会;
关键词
D O I
10.1039/c4ta02583k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Two-dimensional Ti3C2, also known as "MXene", was oxidized in air under two different oxidizing regimes in order to produce carbon-supported TiO2. In situ TEM analysis coupled with Raman spectroscopy revealed the formation of either anatase nanoparticles or planar rutile nanocrystals, which were controlled by the time, temperature and heating rate.
引用
收藏
页码:14339 / 14343
页数:5
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