Anodic stripping voltammetry at bismuth-coated and uncoated carbon microdisk electrodes: Application to trace metals analysis in food samples

This article reports on the Performance of a bismuth-coated carbon microdisk electrode (BiFmuE) for the determination of trace heavy metals by anodic stripping voltammetry (ASV). The BiFmuE was prepared by electrodeposition of a metallic bismuth film onto the microdisk, by applying an in-situ electroplating procedure. To test the performance of the BiFmuE, ASV measurements were performed on synthetic solutions containing Cd2+, Pb2+, and Cu2+ as target ions. The results indicated that cadmium and lead gave well-defined ASV peaks with no interference, and their quantitative determination could be carried out straightforwardly. In particular, linear calibration curves over the range 5.0 x 10(-8)-1.0 x 10(-6) M for both ions, and detection limits of 7.8 and 2.9 nM, for cadmium and lead, respectively, after applying a 60 see preconcentration step, were obtained. The reproducibility was also satisfactory, the relative standard deviation (RSD) being within 2.5% for both ions. Copper, instead, gave an ASV response that, in most experimental conditions, overlapped with that of bismuth. This circumstance made the determination of copper at the BiFmuE difficult. Since the latter element could be detected reliably at the uncoated carbon microdisk electrode (CmuE), both BiFmuE and CmuE were employed, respectively, for the determination of lead and copper ions in drinking water, wine, and tomato sauce.