Nitrogen and Hydrogen Adsorption by an Organic Microporous Crystal

被引：123

作者：

Msayib, Kadhum J. ^{[1
]}

Book, David ^{[3
]}

Budd, Peter M. ^{[2
]}

Chaukura, Nhamo ^{[2
]}

Harris, Kenneth D. M. ^{[1
]}

Helliwell, Madeleine ^{[2
]}

Tedds, Steven ^{[3
]}

Walton, Allan ^{[3
]}

Warren, John E. ^{[4
]}

Xu, Mingcan ^{[1
]}

McKeown, Neil B. ^{[1
]}

机构：

[1] Cardiff Univ, Sch Chem, Cardiff CF10 AT, S Glam, Wales

[2] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[3] Univ Birmingham, Sch Met & Mat, Coll Engn & Phys Sci, Birmingham B15 2TT, W Midlands, England

[4] CCLRC Daresbury Lab, Warrington WA4 4AD, Cheshire, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 18期

基金：

英国工程与自然科学研究理事会;

关键词：

adsorption; hydrogen storage; interconnectivity; microporous materials; organic zeolites; STORAGE; POLYMERS; CHEMISTRY; SORPTION; CAVITIES; DESIGN; NETS; UREA; GAS;

D O I：

10.1002/anie.200900234

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Quick on the uptake: Following its identification during a targeted search, the intriguing crystal structure of 3,3 ,4,4 -tetra(trimethylsilylethynyl) biphenyl was investigated. Simple removal of the included solvent provides an organic crystal with an open microporous structure that has a striking similarity to that of zeolite A (see picture). Reversible adsorption of nitrogen and hydrogen gases at 77 K confirms that the microporosity is permanent. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3273 / 3277

页数：5

共 77 条

[41] Mascal M., 1996, ANGEW CHEM, V108, P2348
[42] McKeown N. B., 2006, ANGEW CHEM, V118, P1836
[43] A phthalocyanine clathrate of cubic symmetry containing interconnected solvent-filled voids of nanometer dimensions
McKeown, NB
Makhseed, S
Msayib, KJ
Ooi, LL
Helliwell, M
Warren, JE
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (46) : 7546 - 7549
[44] Towards polymer-based hydrogen storage materials: Engineering ultramicroporous cavities within polymers of intrinsic microporosity
McKeown, NB
Ghanem, BS
Msayib, KJ
Budd, PM
Tattershall, CE
Mahmood, K
Tan, S
Book, D
Langmi, HW
Walton, A
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (11) : 1804 - 1807
[45] Microporous polymers as potential hydrogen storage materials
McKeown, Neil B.
Budd, Peter M.
Book, David
[J]. MACROMOLECULAR RAPID COMMUNICATIONS, 2007, 28 (09) : 995 - 1002
[46] Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage
McKeown, Neil B.
Budd, Peter M.
[J]. CHEMICAL SOCIETY REVIEWS, 2006, 35 (08) : 675 - 683
[47] Gas storage in nanoporous materials
Morris, Russell E.
Wheatley, Paul S.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (27) : 4966 - 4981
[48] HIGH DIASTEREOFACIAL SELECTIVITY IN NUCLEOPHILIC ADDITIONS TO CHIRAL ACYLSILANES
NAKADA, M
URANO, Y
KOBAYASHI, S
OHNO, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (14) : 4826 - 4827
[49] Electrochemical and ferromagnetic couplings in 4,4′,4"-( 1,3,5-benzenetriyl)tris(phenoxyl) radical formation
Nishide, H
Doi, R
Oyaizu, K
Tsuchida, E
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (05) : 1680 - 1685
[50] CH/π hydrogen bonds in crystals
Nishio, M
[J]. CRYSTENGCOMM, 2004, 6 : 130 - 158

← 1 2 3 4 5 6 7 8 →