Enantioselective hydrogenation of alpha- and beta-functionalized ketones by Ru(II){AMPP} catalysts

被引：15

作者：

Hapiot, F

Agbossou, F

Mortreux, A

机构：

[1] ENSCL,URA CNRS 402,CATALYSE HETEROGENE & HOMOGENE LAB,F-59652 VILLENEUVE DASCQ,FRANCE

[2] UNIV SCI & TECH LILLE FLANDRES ARTOIS,FAC SCI,LAB PHYSICOCHIM INTERFACES & APPLICAT,F-62307 LENS,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 17期

关键词：

D O I：

10.1016/S0957-4166(97)00319-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Neutral ruthenium complexes bearing aminophosphine-phosphinite ligands have been applied in the enantioseIective hydrogenation of alpha- (5-7) and beta- (8-10) functionalized ketones. The corresponding hydroxycompounds are produced with enantiomeric excesses up to 63 and 85% respectively for the two types of substrates. (C) 1997 Elsevier Science Ltd.

引用

页码：2881 / 2884

页数：4

共 17 条

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