Hybrid materials for immobilization of MP-11 catalyst

被引：121

作者：

Pisklak, Thomas J.

Macias, Minedys

Coutinho, Decio H.

Huang, Rita S.

Balkus, Kenneth J., Jr. ^{[1
]}

机构：

[1] Univ Texas, Dept Chem, Richardson, TX 75080 USA

[2] Univ Texas, UTD Nanotech Inst, Richardson, TX 75080 USA

来源：

TOPICS IN CATALYSIS | 2006年 / 38卷 / 04期

关键词：

immobilization; metal organic framework; microperoxidase-11; mesoporous materials; oxidation;

D O I：

10.1007/s11244-006-0025-6

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Microperoxidase-11(MP-11) has been immobilized for the first time in hybrid periodic mesoporous organosilica (PMO) materials and in a nano-crystalline metal organic framework (MOF). Microperoxidase-11 was physically absorbed from solution into the periodic mesoporous organosilica MBS and functionalized derivatives of MBS as well as in the 3-dimensional [Cu(OOC-C6H4-C6H4-COO)center dot 1/2C(6)H(12)N(2)]eta metal organic framework. The conversion of Amplex(R) UltraRed and methylene blue to their respective oxidation products by immobilized MP-11 was determined.

引用

收藏

页码：269 / 278

页数：10

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