PS-PEG resin-supported palladium-MOP complexes.: Application in asymmetric π-allylic reduction

被引：30

作者：

Hocke, H ^{[1
]}

Uozumi, Y ^{[1
]}

机构：

[1] IMS, Okazaki, Aichi 4448787, Japan

来源：

TETRAHEDRON | 2004年 / 60卷 / 41期

基金：

日本科学技术振兴机构; 日本学术振兴会;

关键词：

MOP; immobilized recyclable catalysts; asymmetric catalysis; pi-allylic reduction;

D O I：

10.1016/j.tet.2004.07.093

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Homochiral palladium complexes of polymeric 2'-, 6-, and 6'-anchored 2-diphenylphosphino-1,1'-binaphthyl (MOP) ligands were prepared on polystyrene-poly(ethylene glycol) (PS-PEG) resin. The PS-PEG resin-supported palladium-MOP complexes exhibited high catalytic activity, stereoselectivity (up to 80% ee), and recyclability (six times) in the asymmetric allylic reduction of 1-vinyl-1,2,3,4-tetrahydronaphth-1-yl benzoate to give 1-vinyl-1,2,3,4-tetrahydronaphthalene. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：9297 / 9306

页数：10

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