Electrodeposition of In+As thin film alloys and their conversion to InAsxP1-x by PH3 treatment

被引:9
作者
Dalchiele, E
Cattarin, S
Musiani, M
Casellato, U
Guerriero, P
Rossetto, G
机构
[1] INST FIS,FAC INGN,MONTEVIDEO 11000,URUGUAY
[2] CNR,IPELP,I-35127 PADUA,ITALY
[3] CNR,ICTIMA,I-35127 PADUA,ITALY
来源
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1996年 / 418卷 / 1-2期
关键词
indium; arsenic; In + As alloys; thin films; electrodeposition;
D O I
10.1016/S0022-0728(96)04776-6
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The codeposition of In+As alloys has been investigated as a preliminary step for the preparation of thin polycrystalline InAs and InAsxP1-x films. Alloys of composition ranging from large excess In to excess As could be obtained by a suitable choice of bath and deposition conditions. Stoichiometric 1:1 deposits have been converted to InAs by simple thermal treatment. In+As alloys with excess In annealed under PH3 flow resulted in deposits consisting of two phases, an InAsxP1-x phase with x in the range 0.25 to 1 and and almost pure InP. Photoelectrochemical investigations showed that only the latter species was photoactive.
引用
收藏
页码:83 / 89
页数:7
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