Synthesis and characterization of a C-60-pentacene monoadduct

被引：40

作者：

Mack, J

Miller, GP

机构：

[1] Department of Chemistry, University of New Hampshire, Durham

来源：

FULLERENE SCIENCE AND TECHNOLOGY | 1997年 / 5卷 / 03期

关键词：

D O I：

10.1080/15363839708015911

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

C-60 reacts with 1 equivalent of pentacene to give a C-60-pentacene monoadduct in 59% yield. H-1 and C-13 NMR data confirm a C-2v Symmetric structure for the monoadduct consistent with C-60 cycloaddition across central carbon atoms 6 and 13 of pentacene. Seven bispentacene adducts are formed in 13% overall yield.

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页码：607 / 614

页数：8

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