Quantitative electrostatic force microscopy-phase measurements

被引:82
作者
Lei, CH [1 ]
Das, A [1 ]
Elliott, M [1 ]
Macdonald, JE [1 ]
机构
[1] Cardiff Univ, Sch Phys & Astron, Cardiff CF24 3YB, S Glam, Wales
关键词
D O I
10.1088/0957-4484/15/5/038
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The phase mode of electrostatic force microscopy (EFM-phase) is a scanning probe microscopy (SPM) technique used to measure electrostatic force gradient. EFM-phase has a higher resolution than scanning Kelvin probe microscopy (SKPM or SKM), but unlike SKPM it does not yield a direct measurement of local potential. Analytical calculations of tip-surface capacitances and their gradients are presented, and the origin of the measurement resolution in EFM-phase and SKPM is explained based on the calculation results. We show that EFM-phase data fit the analytical calculation well, and can be interpreted using a simple analytic model, which allows phase shift to be related to the local surface potential. The analytic formula is easy to calibrate and can be used to convert the EFM-phase data to potential data. This procedure is demonstrated on a poly-(3-hexylthiophene-2,5-diyl) (P3HT) thin film, contacted with Au electrodes, and the potential distributions of the Au/P3HT/Au structure under various biases are presented.
引用
收藏
页码:627 / 634
页数:8
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