Insight in the outside: New applications of low-energy ion scattering

被引:17
作者
Brongersma, HH
Gildenpfennig, A
van der Gon, AWD
van de Grampel, RD
Jansen, WPA
Knoester, A
Laven, J
Viitanen, MM
机构
[1] Eindhoven Univ Technol, Dept Appl Phys, NL-5600 MB Eindhoven, Netherlands
[2] Calipso BV, NL-5600 MB Eindhoven, Netherlands
[3] Eindhoven Univ Technol, Lab Polymer Chem & Coatings Technol, NL-5600 MB Eindhoven, Netherlands
关键词
surface science; LEIS; ISS; ion spectroscopy; surface analysis; catalysts;
D O I
10.1016/S0168-583X(01)01314-3
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Low energy ion scattering is used to selectively probe the outermost atomic layer of the surface. The development of double toroidal analyzers has improved the detection sensitivity of low energy ion scattering by orders of magnitude. The features of these analyzers are discussed. It is shown that the absence of matrix effects makes it possible to quantify the surface density of fluorine in polymers with a LiF(1 0 0) surface. The extreme surface sensitivity of LEIS also enables one to study intramolecular segregation processes. As an example the aging of a polypropylene surface that has been activated with atomic oxygen is described. As an example of the LEIS analysis of highly dispersed isolating surfaces, the formation of coke on a commercial three-way catalyst is discussed. (C) 2002 Published by Elsevier Science B.V.
引用
收藏
页码:11 / 18
页数:8
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