Synthesis and structure of amino-functionalized cyclopentadienyl vanadium complexes and evaluation of their butadiene polymerization behavior

被引：23

作者：

Bradley, S ^{[1
]}

Camm, KD ^{[1
]}

Furtado, SJ ^{[1
]}

Gott, AL ^{[1
]}

McGowan, PC ^{[1
]}

Podesta, TJ ^{[1
]}

Thornton-Pett, M ^{[1
]}

机构：

[1] Univ Leeds, Dept Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 16期

关键词：

D O I：

10.1021/om020170f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have synthesized a number of bis-1,1,-amino-functionalized vanadocenes and vanadocene monochlorides; the bis-1,1,-amino-functiohalized vanadocenes represent the first examples of structurally characterized compounds of this type, and bis-1,1,-amion-functionalized vanadocene monochlorides represent the first example synthesized and characterized. We report the catalytic behavior of some of the complexes toward butadiene and observe that amino-functionalized, cyclopentadienyl vanadium phosphine chloride complexes behave much differently from their nonfunctionalized cyclopentadienyl derivatives.

引用

页码：3443 / 3453

页数：11

共 44 条

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