Synthesis and molecular structure of a tricyclic stannasiloxane containing a novel SiSn3O3F2 structural motif

被引：10

作者：

Beckmann, J

Jurkschat, K ^{[1
]}

Schürmann, M

Suter, D

Willem, R

机构：

[1] Univ Dortmund, Fachbereich Chem, Lehrstuhl Anorgan Chem 2, D-44221 Dortmund, Germany

[2] Free Univ Brussels, VUB, High Resolut NMR Ctr HNMR, B-1050 Brussels, Belgium

[3] Univ Dortmund, Fachbereich Phys, Lehrstuhl Expt Phys 3, D-44221 Dortmund, Germany

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 18期

关键词：

D O I：

10.1021/om0203577

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of the fluorine-substituted stannasiloxane complex cyclo-Ph2Si(OSnt-Bu-2)(2)O.t-Bu2SnF2 (7) is reported, and its molecular structure has been determined by single-crystal X-ray diffraction analysis.

引用

页码：3819 / 3822

页数：4

共 19 条

[1] [Anonymous], 1992, INT TABLES CRYSTALLO, VC
[2] Stannasiloxanes: from rings to polymers
Beckmann, J
Jurkschat, K
[J]. COORDINATION CHEMISTRY REVIEWS, 2001, 215 : 267 - 300
[3] Reaction of (t-Bu2SnO)3 with organohalosilanes.: Simple formation of open-chain and cyclic stannasiloxanes
Beckmann, J
Mahieu, B
Nigge, W
Schollmeyer, D
Schürmann, M
Jurkschat, K
[J]. ORGANOMETALLICS, 1998, 17 (26) : 5697 - 5712
[4] Beckmann J, 1998, MAIN GROUP MET CHEM, V21, P113
[5] Reactions of [t-Bu2SnO]3 with [t-BuX2Si]2 (X = F, Cl).: Syntheses and structures of novel stannasiloxanes and of [(t-Bu2FSn)2O]2, the first fluorine-containing tetraorganodistannoxane
Beckmann, J
Biesemans, M
Hassler, K
Jurkschat, K
Martins, JC
Schurmann, M
Willem, R
[J]. INORGANIC CHEMISTRY, 1998, 37 (19) : 4891 - 4897
[6] STERICALLY HINDERED ORGANOTIN COMPOUNDS .3. THE REACTION BETWEEN DI-TERT-BUTYLTIN OXIDE AND ORGANOBORONIC ACIDS
BROWN, P
MAHON, MF
MOLLOY, KC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (24): : 3503 - 3509
[7] A unique self-assembled tricyclic stannasiloxane containing a planar Sn3SiO5 fused 6.4.4 tricyclic ring system
Cervantes-Lee, F
Sharma, HK
Haiduc, I
Pannell, KH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (01): : 1 - 2
[8] Main group and transition metal compounds with silanediolate [R2SiO2]2- and α,ω-siloxane diolate [O(R2SiO)n]2- ligands
King, L
Sullivan, AC
[J]. COORDINATION CHEMISTRY REVIEWS, 1999, 189 : 19 - 57
[9] HETEROCYCLIC-SYSTEMS CONTAINING TIN(IV) .10. CONTROL OF 3-CENTER INTERACTIONS X...SN-HAL IN STANNOCANES BY HALIDE TYPE
KOLB, U
BEUTER, M
DRAGER, M
[J]. INORGANIC CHEMISTRY, 1994, 33 (20) : 4522 - 4530
[10] Disiloxanediolates and polyhedral metallasilsesquioxanes of the early transition metals and f-elements
Lorenz, V
Fischer, A
Giessmann, S
Gilje, JW
Gun'ko, Y
Jacob, K
Edelmann, FT
[J]. COORDINATION CHEMISTRY REVIEWS, 2000, 206 : 321 - 368

← 1 2 →