Colloidal Route for Preparing Optical Thin Films of Nanoporous Metal-Organic Frameworks

被引：229

作者：

Horcajada, Patricia ^{[2
]}

Serre, Christian ^{[2
]}

Grosso, David ^{[1
]}

Boissiere, Cedric ^{[1
]}

Perruchas, Sandrine ^{[4
]}

Sanchez, Clement ^{[1
]}

Ferey, Gerard ^{[2
,3
]}

机构：

[1] Univ Paris 06, Lab Chim Mat Condensee Paris, CNRS, UMR 7574, F-75252 Paris 05, France

[2] Univ Versailles, Inst Lavoisier, CNRS, UMR 8180, F-78035 Versailles, France

[3] Inst Univ France, F-75005 Paris, France

[4] Ecole Polytech, Phys Mat Condensee Lab, CNRS, UMR 7643, F-91128 Palaiseau, France

来源：

ADVANCED MATERIALS | 2009年 / 21卷 / 19期

关键词：

GROWTH; SEPARATION; POROSITY; SOLIDS; MIL-53;

D O I：

10.1002/adma.200801851

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Colloids of a highly flexible porous metal-organic framework (MOF) have been prepared using nontoxic and easily removable solvents. Furthermore, a simple dip-coating method for the preparation of optical-quality thin films of the MOF has been developed. The homogeneous thin film exhibits reversible flexibility, as has been proven by environmental ellipsometry.

引用

页码：1931 / 1935

页数：5

共 32 条

[1] Pyrolysis, crystallization, and sintering of mesostructured titania thin films assessed by in situ thermal ellipsometry
Bass, John D.
Grosso, David
Boissiere, Cedric
Sanchez, Clement
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (25) : 7882 - 7897
[2] Oriented growth of the metal organic framework Cu3(BTC)2(H2O)3•xH2O tunable with functionalized self-assembled monolayers
Biemmi, Enrica
Scherb, Camilla
Bein, Thomas
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (26) : 8054 - +
[3] Porosity and mechanical properties of mesoporous thin films assessed by environmental ellipsometric porosimetry
Boissiere, C
Grosso, D
Lepoutre, S
Nicole, L
Bruneau, AB
Sanchez, C
[J]. LANGMUIR, 2005, 21 (26) : 12362 - 12371
[4] INDEXING OF POWDER DIFFRACTION PATTERNS FOR LOW-SYMMETRY LATTICES BY THE SUCCESSIVE DICHOTOMY METHOD
BOULTIF, A
LOUER, D
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1991, 24 (pt 6) : 987 - 993
[5] Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47
Bourrelly, S
Llewellyn, PL
Serre, C
Millange, F
Loiseau, T
Férey, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (39) : 13519 - 13521
[6] Carvajal J.R., 1990, ABSTR SATELL MEET PO, P127
[7] MAGNETIC-PROPERTIES AND MOSSBAUER-SPECTRA OF SEVERAL IRON(III)-DICARBOXYLIC ACID COMPLEXES
DZIOBKOWSKI, CT
WROBLESKI, JT
BROWN, DB
[J]. INORGANIC CHEMISTRY, 1981, 20 (03) : 671 - 678
[8] Photonic and nanobiophotonic properties of luminescent lanthanide-doped hybrid organic- inorganic materials
Escribano, Purificacion
Julian-Lopez, Beatriz
Planelles-Arago, Jose
Cordoncillo, Eloisa
Viana, Bruno
Sanchez, Clement
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (01) : 23 - 40
[9] Hydrogen adsorption in the nanoporous metal-benzenedicarboxylate M(OH)(O2C-C6H4-CO2) (M = Al3+, Cr3+), MIL-53
Férey, G
Latroche, M
Serre, C
Millange, F
Loiseau, T
Percheron-Guégan, A
[J]. CHEMICAL COMMUNICATIONS, 2003, (24) : 2976 - 2977
[10] Hybrid porous solids:: past, present, future
Ferey, Gerard
[J]. CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) : 191 - 214

← 1 2 3 4 →