Synthesis of CuInS2 quantum dots on TiO2 porous films by solvothermal method for absorption layer of solar cells

被引：55

作者：

Feng, Jiamin ^{[1
]}

Han, Jianjun ^{[1
]}

Zhao, Xiujian ^{[1
]}

机构：

[1] Wuhan Univ Technol, Key Lab Silicate Mat Sci & Engn, Wuhan 430070, Hubei, Peoples R China

来源：

PROGRESS IN ORGANIC COATINGS | 2009年 / 64卷 / 2-3期

关键词：

CuInS2; nano-particles; Heat-treatment; Quantum dots; TiO2 porous films; THIN-FILMS; OPTICAL-PROPERTIES; SPRAY PYROLYSIS; PBS;

D O I：

10.1016/j.porgcoat.2008.08.022

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Copper indium disulfide (CuInS2) nano-particles have been synthesized by solvothermal method for absorption layer of solar cells. The CuInS2 nano-particles can be adsorbed in pores of TiO2 porous films. The effects of heat-treatment on crystalline structures and sizes of the CuInS2 nano-particles were investigated. Crystalline structures and sizes were characterized by X-ray diffraction (XRD) and transmission electron microscope (TEM) investigations. Surface morphologies and optical properties were studied by field-emission scanning electron microscope (FESEM) and UV-vis spectra when CuInS2 were absorbed on TiO2 films. The results show that the CuInS2 quantum dots (size is smaller than 10nm) can be synthesized by solvothermal method at 150,C. CuInS2 particles sizes increase with the rise of reaction temperature and time. The CuInS2 quantum dots can be adsorbed on TiO2 films well and high-absorptive anodic electrode of solar cells can be prepared. Blue shift of absorption edge was observed as the sizes of CuInS2 quantum dots decreased. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：268 / 273

页数：6

共 21 条

[11] IN2O3/CDS/CUINS2 THIN-FILM SOLAR-CELL WITH 9.7-PERCENT EFFICIENCY [J].

OGAWA, Y ;

JAGERWALDAU, A ;

HASHIMOTO, Y ;

ITO, K .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1994, 33 (12B) :L1775-L1777

[12] PREPARATION AND CHARACTERIZATION OF CHEMICALLY DEPOSITED CUINS2 THIN-FILMS [J].

PADAM, GK ;

RAO, SUM .

SOLAR ENERGY MATERIALS, 1986, 13 (04) :297-305

[13] Photovoltaic characteristics of CuInS2/CdS solar cell by electron beam evaporation [J].

Park, GC ;

Chung, HD ;

Kim, CD ;

Park, HR ;

Jeong, WJ ;

Kim, JU ;

Gu, HB ;

Lee, KS .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1997, 49 (1-4) :365-374

[14] ABSORPTION-COEFFICIENT MEASUREMENTS FOR VACUUM-DEPOSITED CUTERNARY THIN-FILMS [J].

SUN, LY ;

KAZMERSKI, LL ;

CLARK, AH ;

IRELAND, PJ ;

MORTON, DW .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1978, 15 (02) :265-268

[15] FABRICATION AND ANALYSIS OF ALL-SPRAYED CUINS2/ZNO SOLAR-CELLS [J].

TIWARI, AN ;

PANDYA, DK ;

CHOPRA, KL .

SOLAR CELLS, 1987, 22 (04) :263-273

[16] ELECTRICAL AND OPTICAL-PROPERTIES OF SINGLE-PHASE CUINS2 FILMS PREPARED USING SPRAY PYROLYSIS [J].

TIWARI, AN ;

PANDYA, DK ;

CHOPRA, KL .

THIN SOLID FILMS, 1985, 130 (3-4) :217-230

[17] QUANTUM-SIZED PBS, CDS, AG2S, SB2S3, AND BI2S3 PARTICLES AS SENSITIZERS FOR VARIOUS NANOPOROUS WIDE-BANDGAP SEMICONDUCTORS [J].

VOGEL, R ;

HOYER, P ;

WELLER, H .

JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (12) :3183-3188

[18]

WALTER T, 1996, CRYST RES TECHNOL, V31, P431

[19] Solar cells based on CuInS2 thin films through sulfurization of precursors prepared by reactive sputtering with H2S gas [J].

Watanabe, T ;

Matsui, M .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1996, 35 (03) :1681-1684

[20] Fabrication and characterization of CuIn(SxSe1-x)(2) thin films deposited by rf sputtering [J].

Yamamoto, Y ;

Yamaguchi, T ;

Demizu, Y ;

Tanaka, T ;

Yoshida, A .

THIN SOLID FILMS, 1996, 281 :372-374

← 1 2 3 →