Thermodynamic Aspects of Electrocatalytic CO2 Reduction in Acetonitrile and with an Ionic Liquid as Solvent or Electrolyte

被引:184
作者
Matsubara, Yasuo [1 ]
Grills, David C. [2 ]
Kuwahara, Yutaka [3 ]
机构
[1] Kanagawa Univ, Dept Mat & Life Chem, Kanagawa Ku, Yokohama, Kanagawa 2218686, Japan
[2] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA
[3] Kumamoto Univ, Grad Sch Sci & Technol, Dept Appl Chem & Biochem, Chuo Ku, Kumamoto 8608555, Japan
来源
ACS CATALYSIS | 2015年 / 5卷 / 11期
关键词
N-HETEROCYCLIC CARBENE; KOHN-SHAM ORBITALS; CARBON-DIOXIDE; ELECTROCHEMICAL REDUCTION; HOMOGENEOUS ELECTROCATALYSTS; MOLECULAR ELECTROCATALYSTS; IMIDAZOLIUM CARBOXYLATES; SELECTIVE CONVERSION; RHENIUM(I) COMPLEXES; HYDROGEN CARBONATES;
D O I
10.1021/acscatal.5b00656
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
[No abstract available]
引用
收藏
页码:6440 / 6452
页数:13
相关论文
共 118 条
[21]   Catalysis of the electrochemical reduction of carbon dioxide [J].
Costentin, Cyrille ;
Robert, Marc ;
Saveant, Jean-Michel .
CHEMICAL SOCIETY REVIEWS, 2013, 42 (06) :2423-2436
[22]   A Local Proton Source Enhances CO2 Electroreduction to CO by a Molecular Fe Catalyst [J].
Costentin, Cyrille ;
Drouet, Samuel ;
Robert, Marc ;
Saveant, Jean-Michel .
SCIENCE, 2012, 338 (6103) :90-94
[23]   Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis [J].
Costentin, Cyrille ;
Drouet, Samuel ;
Robert, Marc ;
Saveant, Jean-Michel .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (27) :11235-11242
[24]  
Cox B. G., 2013, ACIDS BASES SOLVENT
[25]   The Influence of the Acidity of Ionic Liquids on Catalysis [J].
Cui, Xinjiang ;
Zhang, Shiguo ;
Shi, Feng ;
Zhang, Qinghua ;
Ma, Xiangyuan ;
Lu, Liujin ;
Deng, Youquan .
CHEMSUSCHEM, 2010, 3 (09) :1043-1047
[26]   Selective Conversion of CO2 to CO with High Efficiency Using an Inexpensive Bismuth-Based Electrocatalyst [J].
DiMeglio, John L. ;
Rosenthal, Joel .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (24) :8798-8801
[27]   Hydrogen bonds in imidazolium ionic liquids [J].
Dong, Kun ;
Zhang, Suojiang ;
Wang, Daxi ;
Yao, Xiaoqian .
JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (31) :9775-9782
[28]   Development of Molecular Electrocatalysts for CO2 Reduction and H2 Production/Oxidation [J].
Dubois, M. Rakowski ;
Dubois, Daniel L. .
ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (12) :1974-1982
[29]   Organocatalysis by N-heterocyclic, carbenes [J].
Enders, Dieter ;
Niemeier, Oliver ;
Henseler, Alexander .
CHEMICAL REVIEWS, 2007, 107 (12) :5606-5655
[30]  
Espenson J.H., 1995, CHEM KINETICS REACTI, V2nd, P70