All Kinds of Reactivity: Recent Breakthroughs in Metal-Catalyzed Alkyne Chemistry

被引：45

作者：

Anaya de Parrodi, Cecilia ^{[2
]}

Walsh, Patrick J. ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA

[2] Univ Americas Puebla, Dept Ciencias Quim Biol, Cholula 72820, Mexico

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 26期

关键词：

alkynes; bimetallic catalysts; homogeneous catalysis; hydrogen bonds; N ligands; TERMINAL ALKYNES; BASE COMPLEX; BIFUNCTIONAL CATALYST; ASYMMETRIC-SYNTHESIS; EFFICIENT SYNTHESIS; ALDEHYDES; HYDRATION; ADDITIONS; YNAMIDES; ESTERS;

D O I：

10.1002/anie.200900900

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkynes of reactions: Recent breakthroughs in metal-catalyzed alkyne reactions, which expand the synthetic utility of alkynes, have been achieved. These approaches broaden the range of alkynes that are accessible by C-N and C-C bond-forming reactions and demonstrate that the use of bifunctional heterobimetallic catalysts can lead to new reactivity and excellent enantioselectivity (see scheme). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4679 / 4682

页数：4

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