Effect of TMEDA on Iron-Catalyzed Coupling Reactions of ArMgX with Alkyl Halides

被引：198

作者：

Noda, Daisuke ^{[2
]}

Sunada, Yusuke ^{[1
]}

Hatakeyama, Takuji ^{[3
]}

Nakamura, Masaharu ^{[3
]}

Nagashima, Hideo ^{[1
,2
]}

机构：

[1] Kyushu Univ, Inst Mat Chem & Engn, Fukuoka 8168580, Japan

[2] Kyushu Univ, Grad Sch Engn Sci, Fukuoka 8168580, Japan

[3] Kyoto Univ, Inst Chem Res, Int Res Ctr Elements Sci, Kyoto 6110011, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 17期

关键词：

GRIGNARD-REAGENTS; COMPLEXES; REACTIVITY;

D O I：

10.1021/ja901262g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new reaction mechanism for the iron-catalyzed cross-coupling reaction of ArMgX with alkyl halides using (TMEDA)FeAr2 and (TMEDA)Fe(Ar)Br is proposed on the basis of the isolation and reaction of these organoiron intermediates.

引用

页码：6078 / +

页数：3

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