Metal-organic framework composites

被引:2007
作者
Zhu, Qi-Long [1 ]
Xu, Qiang [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Ikeda, Osaka 5638577, Japan
关键词
POROUS COORDINATION POLYMERS; MESOPOROUS SILICA NANOPARTICLES; ORGANOMETALLIC CVD-PRECURSORS; SHELL MAGNETIC MICROSPHERES; GRAPHITE OXIDE COMPOSITES; ENHANCED HYDROGEN STORAGE; HIGHLY-ACTIVE CATALYSTS; WALLED CARBON NANOTUBES; SOLID-PHASE EXTRACTION; HIGH-SURFACE-AREA;
D O I
10.1039/c3cs60472a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Metal-organic frameworks (MOFs), also known as porous coordination polymers (PCPs), synthesized by assembling metal ions with organic ligands have recently emerged as a new class of crystalline porous materials. The amenability to design as well as fine-tunable and uniform pore structures makes them promising materials for a variety of applications. Controllable integration of MOFs and functional materials is leading to the creation of new multifunctional composites/hybrids, which exhibit new properties that are superior to those of the individual components through the collective behavior of the functional units. This is a rapidly developing interdisciplinary research area. This review provides an overview of the significant advances in the development of diverse MOF composites reported till now with special emphases on the synergistic effects and applications of the composites. The most widely used and successful strategies for composite synthesis are also presented.
引用
收藏
页码:5468 / 5512
页数:45
相关论文
共 419 条
[21]   Metal-Organic Framework Thin Films: From Fundamentals to Applications [J].
Betard, Angelique ;
Fischer, Roland A. .
CHEMICAL REVIEWS, 2012, 112 (02) :1055-1083
[22]   Oriented growth of the metal organic framework Cu3(BTC)2(H2O)3•xH2O tunable with functionalized self-assembled monolayers [J].
Biemmi, Enrica ;
Scherb, Camilla ;
Bein, Thomas .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (26) :8054-+
[23]   Stabilization of graphene quantum dots (GQDs) by encapsulation inside zeolitic imidazolate framework nanocrystals for photoluminescence tuning [J].
Biswal, Bishnu P. ;
Shinde, Dhanraj B. ;
Pillai, Vijayamohanan K. ;
Banerjee, Rahul .
NANOSCALE, 2013, 5 (21) :10556-10561
[24]   Metal-organic framework growth at functional interfaces: thin films and composites for diverse applications [J].
Bradshaw, Darren ;
Garai, Ashesh ;
Huo, Jia .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (06) :2344-2381
[25]   Investigations on crystalline interface within a molecular composite crystal by microscopic techniques [J].
Bres, Etienne F. ;
Ferlay, Sylvie ;
Dechambenoit, Pierre ;
Leroux, Hugues ;
Hosseini, Mir Wais ;
Reyntjens, Steve .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (16) :1559-1562
[26]   Big returns from small fibers: A review of polymer/carbon nanotube composites [J].
Breuer, O ;
Sundararaj, U .
POLYMER COMPOSITES, 2004, 25 (06) :630-645
[27]   Chromium(III) Terephthalate Metal Organic Framework (MIL-101): HF-Free Synthesis, Structure, Polyoxometalate Composites, and Catalytic Properties [J].
Bromberg, Lev ;
Diao, Ying ;
Wu, Huimeng ;
Speakman, Scott A. ;
Hatton, T. Alan .
CHEMISTRY OF MATERIALS, 2012, 24 (09) :1664-1675
[28]   Post-Synthetic Modification of Tagged Metal-Organic Frameworks [J].
Burrows, Andrew D. ;
Frost, Christopher G. ;
Mahon, Mary F. ;
Richardson, Christopher .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (44) :8482-8486
[29]   Highly Luminescent Metal-Organic Frameworks Through Quantum Dot Doping [J].
Buso, Dario ;
Jasieniak, Jacek ;
Lay, Matthew D. H. ;
Schiavuta, Piero ;
Scopece, Paolo ;
Laird, Jamie ;
Amenitsch, Heinz ;
Hill, Anita J. ;
Falcaro, Paolo .
SMALL, 2012, 8 (01) :80-88
[30]   Fast Synthesis of MOF-5 Microcrystals Using Sol-Gel SiO2 Nanoparticles [J].
Buso, Dario ;
Nairn, Kate M. ;
Gimona, Michele ;
Hill, Anita J. ;
Falcaro, Paolo .
CHEMISTRY OF MATERIALS, 2011, 23 (04) :929-934