Carbon-carbon bond formation via the transmetalation of an alkenyl group on azazirconacyclopentene

被引：14

作者：

Honda, T ^{[1
]}

Mori, M ^{[1
]}

机构：

[1] HOKKAIDO UNIV,FAC PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 26期

关键词：

D O I：

10.1021/om960364t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The transmetalation of azazirconacyclopentene 1, prepared by inserting alkyne 8 into azazirconacyclopropane 7, was realized, and the zirconium-carbon bond of complex 1 was transformed to a carbon-carbon bond using a copper(I) salt. Thus, both allyl and formyl groups can be introduced into alkyne carbons in a highly stereoselective manner in a one-pot reaction.

引用

页码：5464 / 5466

页数：3

共 20 条

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