First lanthanide dipolar complexes for second-order nonlinear optics

被引：48

作者：

Sénéchal, K

Toupet, L

Ledoux, I

Zyss, J

Le Bozec, H

Maury, O

机构：

[1] Univ Rennes 1, CNRS, UMR 6509, Inst Chim Rennes, F-35042 Rennes, France

[2] Univ Rennes 1, CNRS, UMR 6626, Grp Mat Condensee & Mat, F-35042 Rennes, France

[3] ENS Cachan, Inst Alembert, Lab Phys Quant Mol, F-94235 Cachan, France

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 19期

关键词：

D O I：

10.1039/b407073a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New push-pull NLO-phores based on lanthanide complexes (Ln = La, Gd, Dy, Yb) featuring an annelated dibutylaminophenyl functionalised terpyridyl ligand have been synthesised and shown to exhibit large first-order hyperpolarizability.

引用

页码：2180 / 2181

页数：2

共 16 条

[1] Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals [J].

Benelli, C ;

Gatteschi, D .

CHEMICAL REVIEWS, 2002, 102 (06) :2369-2387

[2] Lanthanide-containing molecular and supramolecular polymetallic functional assemblies [J].

Bünzli, JCG ;

Piguet, C .

CHEMICAL REVIEWS, 2002, 102 (06) :1897-1928

[3] New bipyridyl ligands bearing azo- and imino-linked chromophores. Synthesis and nonlinear optical studies of related dipolar zinc complexes [J].

Hilton, A ;

Renouard, T ;

Maury, O ;

Le Bozec, H ;

Ledoux, I ;

Zyss, J .

CHEMICAL COMMUNICATIONS, 1999, (24) :2521-2522

[4] LANGMUIR FILM-FORMING AND 2ND-HARMONIC GENERATION PROPERTIES OF LANTHANIDE COMPLEXES [J].

HUANG, CH ;

WANG, KZ ;

XU, GX ;

ZHAO, XS ;

XIE, XM ;

XU, Y ;

LIU, YQ ;

XU, LG ;

LI, TK .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (39) :14397-14402

[5] Introduction: Frontiers in lanthanide chemistry [J].

Kagan, HB .

CHEMICAL REVIEWS, 2002, 102 (06) :1805-1806

[6] Synthesis, photophysical and nonlinear optical properties of macromolecular architectures featuring octupolar tris(bipyridine) ruthenium(II) moieties: Evidence for a supramolecular self-ordering in a dentritic structure [J].

Le Bouder, T ;

Maury, O ;

Bondon, A ;

Costuas, K ;

Amouyal, E ;

Ledoux, I ;

Zyss, J ;

Le Bozec, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (40) :12284-12299

[7] CONFORMATIONAL PROPERTIES OF EU(III) COMPLEXES OF 3,3'-5,3''-POLYMETHYLENE BRIDGED DERIVATIVES OF 2,2'-6,2''-TERPYRIDINE [J].

MALLET, C ;

THUMMEL, RP ;

HERY, C .

INORGANICA CHIMICA ACTA, 1993, 210 (02) :223-231

[8] OPTICAL NONLINEARITIES OF CONJUGATED MOLECULES - STILBENE DERIVATIVES AND HIGHLY POLAR AROMATIC-COMPOUNDS [J].

OUDAR, JL .

JOURNAL OF CHEMICAL PHYSICS, 1977, 67 (02) :446-457

[9] Being excited by lanthanide coordination complexes: Aqua species, chirality, excited-state chemistry, and exchange dynamics [J].

Parker, D ;

Dickins, RS ;

Puschmann, H ;

Crossland, C ;

Howard, JAK .

CHEMICAL REVIEWS, 2002, 102 (06) :1977-2010

[10] Luminescent properties of lanthanide nitrate complexes with substituted bis(benzimidazolyl)pyridines [J].

Petoud, S ;

Bunzli, JCG ;

Schenk, KJ ;

Piguet, C .

INORGANIC CHEMISTRY, 1997, 36 (07) :1345-1353

← 1 2 →