A Two-Dimensional Polymer from the Anthracene Dimer and Triptycene Motifs

被引：173

作者：

Bhola, Radha ^{[1
]}

Payamyar, Payam ^{[2
]}

Murray, Daniel J. ^{[1
]}

Kumar, Bharat ^{[1
]}

Teator, Aaron J. ^{[1
]}

Schmidt, Martin U. ^{[3
]}

Hammer, Sonja M. ^{[3
]}

Saha, Animesh ^{[2
]}

Sakamoto, Junji ^{[2
]}

Schlueter, A. Dieter ^{[2
]}

King, Benjamin T. ^{[1
]}

机构：

[1] Univ Nevada, Dept Chem, Reno, NV 89557 USA

[2] ETH, Inst Polymers, Polymer Chem Lab, Dept Mat, CH-8093 Zurich, Switzerland

[3] Goethe Univ Frankfurt, Inst Inorgan & Analyt Chem, D-60438 Frankfurt, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 38期

基金：

美国国家科学基金会;

关键词：

COVALENT ORGANIC FRAMEWORK; SOLID-STATE; MOLECULAR-CRYSTALS; GRAPHENE; 2D; EXFOLIATION; PHOTODIMERIZATION; DELAMINATION; NANOSHEETS; CHEMISTRY;

D O I：

10.1021/ja404351p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A two-dimensional polymer (2DP) based on the dimerization of anthraceno groups arranged in a triptycene motif is reported. A photoinduced polymerization is performed in the crystalline state and gives a lamellar 2DP via a crystal-to-crystal (but not single-crystal to single-crystal) transformation. Solvent-induced exfoliation provides monolayer sheets of the 2DP. The 2DP is considered to be a tiling, a mathematical approach that facilitates structural elucidation.

引用

收藏

页码：14134 / 14141

页数：8

相关论文

共 47 条

[1] Single Layer of Polymeric Fe-Phthalocyanine: An Organometallic Sheet on Metal and Thin Insulating Film [J].

Abel, Mathieu ;

Clair, Sylvain ;

Ourdjini, Oualid ;

Mossoyan, Mireille ;

Porte, Louis .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (05) :1203-1205

[2] Single layers of a multifunctional laminar Cu(I,II) coordination polymer [J].

Amo-Ochoa, Pilar ;

Welte, Lorena ;

Gonzalez-Prieto, Rodrigo ;

Sanz Miguel, Pablo J. ;

Gomez-Garcia, Carlos J. ;

Mateo-Marti, Eva ;

Delgado, Salome ;

Gomez-Herrero, Julio ;

Zamora, Felix .

CHEMICAL COMMUNICATIONS, 2010, 46 (19) :3262-3264

[3]

[Anonymous], MAT STUD 4 4

[4] Synthesis of Free-Standing, Monolayered Organometallic Sheets at the Air/Water Interface [J].

Bauer, Thomas ;

Zheng, Zhikun ;

Renn, Alois ;

Enning, Raoul ;

Stemmer, Andreas ;

Sakamoto, Junji ;

Schlueter, A. Dieter .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (34) :7879-7884

[5] Towards 2D and 3D Coordination Polymers: Synthesis of Shape-Persistent Star Monomers with 2,2′:6′,2"-Terpyridin-4′-yl Units at the Periphery [J].

Bauer, Thomas ;

Schlueter, A. Dieter ;

Sakamoto, Junji .

SYNLETT, 2010, (06) :877-880

[6] Delamination of Layered Covalent Organic Frameworks [J].

Berlanga, Isadora ;

Luisa Ruiz-Gonzalez, Maria ;

Maria Gonzalez-Calbet, Jose ;

Fierro, Jose Luis G. ;

Mas-Balleste, Ruben ;

Zamora, Felix .

SMALL, 2011, 7 (09) :1207-1211

[7] Two-Dimensional Polymer Formation on Surfaces: Insight into the Roles of Precursor Mobility and Reactivity [J].

Bieri, Marco ;

Nguyen, Manh-Thuong ;

Groening, Oliver ;

Cai, Jinming ;

Treier, Matthias ;

Ait-Mansour, Kamel ;

Ruffieux, Pascal ;

Pignedoli, Carlo A. ;

Passerone, Daniele ;

Kastler, Marcel ;

Muellen, Klaus ;

Fasel, Roman .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (46) :16669-16676

[8] Reactions between or within molecular crystals [J].

Braga, D ;

Grepioni, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (31) :4002-4011

[9] Photodimerisation of anthracene:: A [4πs+4πs] photochemical cycloaddition [J].

Breton, GW ;

Vang, X .

JOURNAL OF CHEMICAL EDUCATION, 1998, 75 (01) :81-82

[10]

Coelho A.A., 2007, TOPAS ACAD 4 1

← 1 2 3 4 5 →