Aqueous solution fabrication of large-scale arrayed obelisk-like zinc oxide nanorods with high efficiency

被引:87
作者
Wang, Z [1 ]
Qian, XF [1 ]
Yin, J [1 ]
Zhu, ZK [1 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Natl Key Lab Composite Mat, Shanghai 200240, Peoples R China
基金
中国国家自然科学基金;
关键词
zinc oxide; two-dimensional arrays; aqueous solution deposition; nanorods;
D O I
10.1016/j.jssc.2003.10.026
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two-dimensional (2D) arrays of obelisk-like zinc oxide nanorods were successfully synthesized with high efficiency on quartz and glass substrate on a large scale through a simple aqueous solution deposition method with zinc nitrate, ammonia, and ammonium chloride as the precursors. Characterized by XRD, EDS, TEM and SEM, the as-grown zinc oxide rods had a single crystalline obelisk-like hexagonal wurtzite structure with diameters of about 300-400 nm and length up to 5 mum. Both XRD and SEM studies revealed the orientation of ZnO rods, and the orientation of ZnO rods can be controlled easily by temperature, pH of the reaction system and the concentration of reactants. (C) 2004 Elsevier Inc. All rights reserved.
引用
收藏
页码:2144 / 2149
页数:6
相关论文
共 31 条
[1]  
Boyle DS, 2002, CHEM COMMUN, P80, DOI 10.1039/b110079n
[2]   Growth of ZnO single crystal thin films on c-plane (0 0 0 1) sapphire by plasma enhanced molecular beam epitaxy [J].
Chen, YF ;
Bagnall, DM ;
Zhu, ZQ ;
Sekiuchi, T ;
Park, KT ;
Hiraga, K ;
Yao, T ;
Koyama, S ;
Shen, MY ;
Goto, T .
JOURNAL OF CRYSTAL GROWTH, 1997, 181 (1-2) :165-169
[3]   Initial preferred growth in zinc oxide thin films on Si and amorphous substrates by a pulsed laser deposition [J].
Choi, JH ;
Tabata, H ;
Kawai, T .
JOURNAL OF CRYSTAL GROWTH, 2001, 226 (04) :493-500
[4]   Orientation control of ZnO thin film prepared by CVD [J].
Funakubo, H ;
Mizutani, N ;
Yonetsu, M ;
Saiki, A ;
Shinozaki, K .
JOURNAL OF ELECTROCERAMICS, 1999, 4 (Suppl 1) :25-32
[5]  
Govender K, 2002, ADV MATER, V14, P1221, DOI 10.1002/1521-4095(20020903)14:17<1221::AID-ADMA1221>3.0.CO
[6]  
2-1
[7]  
HAN WQ, 1997, SCENCE, V277
[8]   Synthesis of uniform hexagonal prismatic ZnO whiskers [J].
Hu, JQ ;
Li, Q ;
Wong, NB ;
Lee, CS ;
Lee, ST .
CHEMISTRY OF MATERIALS, 2002, 14 (03) :1216-1219
[9]   Chemistry and physics in one dimension: Synthesis and properties of nanowires and nanotubes [J].
Hu, JT ;
Odom, TW ;
Lieber, CM .
ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (05) :435-445
[10]   Room-temperature ultraviolet nanowire nanolasers [J].
Huang, MH ;
Mao, S ;
Feick, H ;
Yan, HQ ;
Wu, YY ;
Kind, H ;
Weber, E ;
Russo, R ;
Yang, PD .
SCIENCE, 2001, 292 (5523) :1897-1899