TCNQ dianion-based coordination polymer whose open framework shows charge-transfer type guest inclusion

被引：124

作者：

Shimomura, Satoru ^{[1
]}

Matsuda, Ryotaro ^{[1
]}

Tsujino, Takashi ^{[1
]}

Kawamura, Takashi ^{[1
]}

Kitagawa, Susumu ^{[1
]}

机构：

[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 51期

关键词：

D O I：

10.1021/ja0660047

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A three-dimensional coordination framework constructed with 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) diainon has been synthesized and structurally characterized. This open framework possessing a highly electron-rich surface has an optical sensing cavity for several aromatics with crystal-to-crystal transformation and strong accommodation, which are based on a charge-transfer interaction with them. Copyright © 2006 American Chemical Society.

引用

页码：16416 / 16417

页数：2

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