Solid state synthesis under supramolecular control of a 2D heterotetratopic self-complementary tecton tailored to halogen bonding

被引：61

作者：

Marras, Giovanni

Metrangolo, Pierangelo

Meyer, Franck

Pilati, Tullio

Resnati, Giuseppe

Vij, Ashwani

机构：

[1] NFMLab DCMIC G Natta, I-20131 Milan, Italy

[2] Politecn Milan, I-22100 Como, Italy

[3] Univ Milan, CNR, ISTM, I-20133 Milan, Italy

[4] AFRL PRSP, Edwards AFB, CA 93524 USA

来源：

NEW JOURNAL OF CHEMISTRY | 2006年 / 30卷 / 10期

关键词：

D O I：

10.1039/b605958a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We describe the synthesis and characterization, by single crystal X-ray analysis, of a 1D heteroditopic self-complementary tecton for halogen bonding. It was designed to also incorporate double bonds and to possess heteropolar pi - pi stacking groups in order to carefully control its supramolecular organization in the solid state. As a result of this supramolecular control, by UV irradiation in the solid state the compound dimerizes forming a 2D heterotetratopic self-complementary tecton tailored to halogen bonding based self-assembly. This 2D tecton crystallizes clathrating chloroform molecules.

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页码：1397 / 1402

页数：6

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