A rational approach to crosslinking of coordination polymers using the photochemical [2+2] cycloaddition reaction

被引：97

作者：

Nagarathinam, Mangayarkarasi ^{[1
]}

Vittal, Jagadese J. ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2006年 / 27卷 / 14期

关键词：

crystal engineering; crystallization; cycloaddition; ladder polymers; metal-polymer complexes; silver; solid-state reactions; stacking interactions; topochemistry; zinc;

D O I：

10.1002/marc.200600246

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polymerization as a result of photocrosslinking is one of the most versatile technologies for producing organic polymers. This article highlights the formation of crosslinking in metal coordination polymers in the solid-state using a photochemical approach and its importance in material science. Past and current developments of solid-state photochemical [2+2] cycloaddition in organic and inorganic systems relevant to the topic are reviewed. The challenges for the coordination chemist in utilising this rational approach to orient the coordination polymers and the scope of this work are delineated.

引用

页码：1091 / 1099

页数：9

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