A novel two-dimensional network self-assembled by the narrowest ladder cations [Cu(CH3COO)(bpe)(H2O)]n+n containing the Cu2(μ-O)2 cores and the dimeric anions [Cu2(nta)2(bpe)]2- through hydrogen-bonding interaction

被引：8

作者：

Li, BL ^{[1
]}

Li, BZ ^{[1
]}

Lang, JP ^{[1
]}

Zhang, Y ^{[1
]}

机构：

[1] Suzhou Univ, Sch Chem & Chem Eng, Suzhou 215006, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 06期

关键词：

ladder; crystal structure; two-dimensional network; hydrogen-bonding;

D O I：

10.1016/S1387-7003(03)00093-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel complex [Cu(CH3COO)(bpe)(H2O)](n) . n/2[Cu-2(nta)(2)(bpe)].6nH(2)O) (bpe = trans-1,2-bis(4-pyridyl)ethylene) was synthesized and characterized. The molecule structure shows that it is composed of the ladder-like double chain cations [Cu(CH3COO)(bpe)(H2O)](n)(n+) and the dimeric anions [Cu-2(nta)(2)(bpe)](2-). Through bridging oxygen atom of the acetate, the Cu-2 (mu-O)(2) core is formed. The ladder-like chain cation is the narrowest ladder [3.422(3) Angstrom]. Two-dimensional undulating network is constructed by the cations and the dimeric anions through hydrogen-bonding interactions. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：725 / 727

页数：3

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