Nitroalkanes as key building blocks for the synthesis of heterocyclic derivatives

被引：55

作者：

Ballini, Roberto ^{[1
]}

Petrini, Marino ^{[1
]}

机构：

[1] Univ Camerino, Dipartimento Sci Chim, Via S Agostino 1, I-62032 Camerino, Italy

来源：

ARKIVOC | 2009年

关键词：

Conjugate addition; heterocycles; Nef reaction; nitro-aldol reaction; nitro-alkanes; ONE-POT SYNTHESIS; EFFICIENT SYNTHESIS; ORGANIC-SYNTHESIS; MICHAEL ADDITION; HENRY REACTION; RING-CLEAVAGE; NITRO; NITROMETHANE; SPIROKETALS; FACILE;

D O I：

10.3998/ark.5550190.0010.912

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nitroalkanes constitute a valuable source of stabilized carbanions for carbon-carbon bond formation through reaction with suitable electrophiles. Reduction of the nitro group or its conversion to a carbonyl group readily provides the necessary amino and oxygenated functions suitable for the preparation of various heterocyclic derivatives.

引用

页码：195 / 223

页数：29