Evidence for the monolayer assembly of poly(vinylpyrrolidone) on the surfaces of silver nanowires

被引：271

作者：

Gao, Y ^{[1
]}

Jiang, P ^{[1
]}

Liu, DF ^{[1
]}

Yuan, HJ ^{[1
]}

Yan, XQ ^{[1
]}

Zhou, ZP ^{[1
]}

Wang, JX ^{[1
]}

Song, L ^{[1
]}

Liu, LF ^{[1
]}

Zhou, WY ^{[1
]}

Wang, G ^{[1
]}

Wang, CY ^{[1
]}

Xie, SS ^{[1
]}

Zhang, JM ^{[1
]}

Shen, AY ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Phys, Ctr Condensed Matter Phys, Beijing 100080, Peoples R China

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2004年 / 108卷 / 34期

关键词：

D O I：

10.1021/jp037116c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The well-defined silver (Ag) nanowires with five-twinned structure have been prepared by polyol reduction in the presence of poly(vinylpyrrolidone) (PVP K-30, 40 000). The obtained Ag nanowires are nearly monodispersed with an average diameter of 70 nm and length of 6 mum. It is confirmed from the results of thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), and Fourier transform Raman spectra (FT-Raman) that one monolayer of the PVP molecules might be absorbed on the surface of the Ag nanowires through Ag-O coordination. On the basis of the experimental analysis, the probable spatial conformation of the PVP molecules is supposed to be that the CH skeleton chain of the PVP is close to the surface of the Ag nanowires. The pyrrolidone ring might be tilted on the surface of the Ag nanowires through Ag:O coordination. These results may provide direct evidence for the role of the PVP molecules in the formation of the Ag nanowires.

引用

页码：12877 / 12881

页数：5

共 35 条

[1] Logic circuits with carbon nanotube transistors [J].

Bachtold, A ;

Hadley, P ;

Nakanishi, T ;

Dekker, C .

SCIENCE, 2001, 294 (5545) :1317-1320

[2] Surface-enhanced Raman scattering [J].

Campion, A ;

Kambhampati, P .

CHEMICAL SOCIETY REVIEWS, 1998, 27 (04) :241-250

[3] Silicon nanowire devices [J].

Chung, SW ;

Yu, JY ;

Heath, JR .

APPLIED PHYSICS LETTERS, 2000, 76 (15) :2068-2070

[4] Indium phosphide nanowires as building blocks for nanoscale electronic and optoelectronic devices [J].

Duan, XF ;

Huang, Y ;

Cui, Y ;

Wang, JF ;

Lieber, CM .

NATURE, 2001, 409 (6816) :66-69

[5] Some interesting properties of metals confined in time and nanometer space of different shapes [J].

El-Sayed, MA .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :257-264

[6] Synthesis, characterization and self-assembly of silver nanowires [J].

Gao, Y ;

Jiang, P ;

Liu, DF ;

Yuan, HJ ;

Yan, XQ ;

Zhou, ZP ;

Wang, JX ;

Song, L ;

Liu, LF ;

Zhou, WY ;

Wang, G ;

Wang, CY ;

Xie, SS .

CHEMICAL PHYSICS LETTERS, 2003, 380 (1-2) :146-149

[7] Rubbing-induced molecular reorientation on an alignment surface of an aromatic polyimide containing cyanobiphenyl side chains [J].

Ge, JJ ;

Li, CY ;

Xue, G ;

Mann, IK ;

Zhang, D ;

Wang, SY ;

Harris, FW ;

Cheng, SZD ;

Hong, SC ;

Zhuang, XW ;

Shen, YR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (24) :5768-5776

[8] Control of thickness and orientation of solution-grown silicon nanowires [J].

Holmes, JD ;

Johnston, KP ;

Doty, RC ;

Korgel, BA .

SCIENCE, 2000, 287 (5457) :1471-1473

[9] Chemistry and physics in one dimension: Synthesis and properties of nanowires and nanotubes [J].

Hu, JT ;

Odom, TW ;

Lieber, CM .

ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (05) :435-445

[10] Photochemical formation of silver nanoparticles in poly(N-vinylpyrrolidone) [J].

Huang, HH ;

Ni, XP ;

Loy, GL ;

Chew, CH ;

Tan, KL ;

Loh, FC ;

Deng, JF ;

Xu, GQ .

LANGMUIR, 1996, 12 (04) :909-912

← 1 2 3 4 →