Band gap engineering and spatial confinement of optical phonon in ZnO quantum dots

被引:103
作者
Lin, Kuo-Feng
Cheng, Hsin-Ming
Hsu, -Cheng Hsu
Hsieh, Wen-Feng
机构
[1] Natl Chiao Tung Univ, Dept Photon, Inst Electroopt Engn, Hsinchu 30050, Taiwan
[2] Ind Technol Res Inst, Mat & Chem Res Labs, Hsinchu 310, Taiwan
关键词
D O I
10.1063/1.2218775
中图分类号
O59 [应用物理学];
学科分类号
摘要
Both band gap engineering and spatial confinement of optical phonon were observed depending upon the size of ZnO quantum dots at room temperature. Size-dependent blueshifts of photoluminescence and absorption spectra reveal the quantum confinement effect. The measured Raman spectral shift and asymmetry for the E-2(high) mode caused by localization of optical phonons agree well with that calculated by using the modified spatial correlation model. (c) 2006 American Institute of Physics.
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页数:3
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共 28 条
[1]   Origin of the optical phonon frequency shifts in ZnO quantum dots [J].
Alim, KA ;
Fonoberov, VA ;
Balandin, AA .
APPLIED PHYSICS LETTERS, 2005, 86 (05) :1-3
[2]   Micro-Raman investigation of optical phonons in ZnO nanocrystals [J].
Alim, KA ;
Fonoberov, VA ;
Shamsa, M ;
Balandin, AA .
JOURNAL OF APPLIED PHYSICS, 2005, 97 (12)
[3]   Infrared dielectric functions and phonon modes of high-quality ZnO films [J].
Ashkenov, N ;
Mbenkum, BN ;
Bundesmann, C ;
Riede, V ;
Lorenz, M ;
Spemann, D ;
Kaidashev, EM ;
Kasic, A ;
Schubert, M ;
Grundmann, M ;
Wagner, G ;
Neumann, H ;
Darakchieva, V ;
Arwin, H ;
Monemar, B .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (01) :126-133
[4]   PREPARATION AND CHARACTERIZATION OF QUANTUM SIZE ZINC-OXIDE - A DETAILED SPECTROSCOPIC STUDY [J].
BAHNEMANN, DW ;
KORMANN, C ;
HOFFMANN, MR .
JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (14) :3789-3798
[5]   Nanowire-based dye-sensitized solar cells [J].
Baxter, JB ;
Aydil, ES .
APPLIED PHYSICS LETTERS, 2005, 86 (05) :1-3
[6]   Photoluminescence dynamics in ensembles of wide-band-gap nanocrystallites and powders [J].
Bergman, L ;
Chen, XB ;
Morrison, JL ;
Huso, J ;
Purdy, AP .
JOURNAL OF APPLIED PHYSICS, 2004, 96 (01) :675-682
[7]   THE EFFECTS OF MICROCRYSTAL SIZE AND SHAPE ON THE ONE PHONON RAMAN-SPECTRA OF CRYSTALLINE SEMICONDUCTORS [J].
CAMPBELL, IH ;
FAUCHET, PM .
SOLID STATE COMMUNICATIONS, 1986, 58 (10) :739-741
[8]   Enhanced resonant Raman scattering and electron-phonon coupling from self-assembled secondary ZnO nanoparticles [J].
Cheng, HM ;
Lin, KF ;
Hsu, HC ;
Lin, CJ ;
Lin, LJ ;
Hsieh, WF .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (39) :18385-18390
[9]   Efficient UV photoluminescence from monodispersed secondary ZnO colloidal spheres synthesized by sol-gel method [J].
Cheng, HM ;
Hsu, HC ;
Chen, SL ;
Wu, WT ;
Kao, CC ;
Lin, LJ ;
Hsieh, WF .
JOURNAL OF CRYSTAL GROWTH, 2005, 277 (1-4) :192-199
[10]   Origin of ultraviolet photoluminescence in ZnO quantum dots: Confined excitons versus surface-bound impurity exciton complexes [J].
Fonoberov, VA ;
Balandin, AA .
APPLIED PHYSICS LETTERS, 2004, 85 (24) :5971-5973