Local structure in (MnS)2x(CuInS2)1-x alloys

被引:8
作者
Pietnoczka, A.
Bacewicz, R.
Schorr, S.
机构
[1] Warsaw Univ Technol, Fac Phys, PL-00662 Warsaw, Poland
[2] Univ Leipzig, Inst Mineral Crystallog & Mat Sci, D-7010 Leipzig, Germany
来源
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE | 2006年 / 203卷 / 11期
关键词
D O I
10.1002/pssa.200669620
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Local structure around Mn atoms in (MnS)(2x)(CuInS2)(1-x) alloys for x <= 0.09 has been determined using near-edge and extended X-ray absorption fine structure (XANES and EXAFS) measured at the Mn K-edge. We found that for the Mn concentration up to 9 at% Mn atoms substitute preferentially for indium in the chalcopyrite lattice. The Mn-S bond length is 2.43 +/- 0.015 angstrom, and is about 2% shorter than the In-S bond length. (c) 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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页码:2746 / 2750
页数:5
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