Bis-N-Annulated Quaterrylene: An Approach to Processable Graphene Nanoribbons

被引：76

作者：

Li, Yan ^{[1
,2
]}

Wang, Zhaohui ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Beijing 100080, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100080, Peoples R China

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 06期

基金：

中国国家自然科学基金;

关键词：

PHOTOPHYSICAL PROPERTIES; POLYARYLENES; DIPORPHYRINS; BISIMIDE;

D O I：

10.1021/ol9002064

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new efficient synthetic method toward processable bis-N-annulated quaterrylene from easily available N-annulated perylene derivatives, which is conducted by DDQ/Sc(OTf)(3) oxidative coupling and ring fusion, is reported. In light of the good processability and the strong electron-donating ability, which is evidenced from the low oxidative potentials, bis-N-annulated quaterrylene is very promising for use as functional components in molecular devices.

引用

收藏

页码：1385 / 1387

页数：3

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