The role of alkoxyl radicals in Gif (GoAgg(v)) chemistry

被引：43

作者：

Snelgrove, DW ^{[1
]}

MacFaul, PA ^{[1
]}

Ingold, KU ^{[1
]}

Wayner, DDM ^{[1
]}

机构：

[1] NATL RES COUNCIL CANADA,STEACIE INST MOLEC SCI,OTTAWA,ON K1A 0R6,CANADA

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 06期

关键词：

D O I：

10.1016/0040-4039(95)02331-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidation of cyclooctane using tert-alkyl hydroperoxides under GoAgg(V) conditions has been examined using selected alkyl hydroperoxides as mechanistic probes. The results indicate that the products are formed by alkoxyl radical-induced reactions, there being no need to invoke any chemistry involving high valent iron-ore species.

引用

页码：823 / 826

页数：4

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