Contribution of slow clusters to the bulk elasticity near the colloidal glass transition

被引:50
作者
Conrad, Jacinta C. [1 ]
Dhillon, Param P.
Weeks, Eric R.
Reichman, David R.
Weitz, David A.
机构
[1] Harvard Univ, Dept Phys, Cambridge, MA 02138 USA
[2] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA
[3] Emory Univ, Dept Phys, Atlanta, GA 30322 USA
[4] Columbia Univ, Dept Chem, New York, NY 10027 USA
[5] Harvard Univ, DEAS, Cambridge, MA 02138 USA
关键词
D O I
10.1103/PhysRevLett.97.265701
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We use confocal microscopy to visualize individual particles near the colloidal glass transition. We identify the most slowly-relaxing particles and show that they form spatially correlated clusters that percolate across the sample. In supercooled fluids, the largest cluster spans the system on short time scales but breaks up on longer time scales. In contrast, in glasses, a percolating cluster exists on all accessible time scales. Using molecular dynamics simulation, we show that these clusters make the dominant contribution to the bulk elasticity of the sample.
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页数:4
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