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Regioselective Ruthenium-Catalyzed Direct Benzylations of Arenes through C-H Bond Cleavages

被引：130
作者：
Ackermann, Lutz [1 ]
Novak, Petr [1 ]
机构：
[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
来源：
ORGANIC LETTERS | 2009年 / 11卷 / 21期
关键词：
CROSS-COUPLING REACTIONS; DIRECT ARYLATIONS; DIHYDROFOLATE-REDUCTASE; PHOSPHINE OXIDES; ARYL CHLORIDES; PALLADIUM; FUNCTIONALIZATION; ACTIVATION; HALIDES; INHIBITORS;
D O I：
10.1021/ol902115f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Highly regioselective ruthenium-catalyzed direct benzylations through C-H bond cleavages were accomplished under remarkably mild, nonacidic reaction conditions, for which experimental studies suggested a SEAr-type mechanism not to be operative.
引用
收藏
页码：4966 / 4969
页数：4
相关论文
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