Kinetic resolution of racemic secondary alcohols via oxidation with Yarrowia lipolytica strains

被引：34

作者：

Fantin, G ^{[1
]}

Fogagnolo, M ^{[1
]}

Medici, A ^{[1
]}

Pedrini, P ^{[1
]}

Fontana, S ^{[1
]}

机构：

[1] Univ Ferrara, Dipartmento Chim, I-44100 Ferrara, Italy

来源：

TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 11期

关键词：

D O I：

10.1016/S0957-4166(00)00185-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cyclic and alicyclic racemic secondary alcohols are kinetically resolved via oxidation with Yarrowia in lipolyticia strains. The comparison of the oxidation reactions with the reductions of the corresponding ketones supports the hypothesis of the presence of two alcohol dehydrogenases with opposite enantioselectivity. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：2367 / 2373

页数：7

共 15 条

[1] BASE-PROMOTED REACTIONS OF EPOXIDES .I. ISOMERIZATION OF SOME CYCLIC AND ACYCLIC EPOXIDES BY LITHIUM DIETHYLAMIDE
CRANDALL, JK
CHANG, LH
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (02) : 435 - &
[2] Combined microbial oxidation and reduction: A new approach to the high-yield synthesis of homochiral unsaturated secondary alcohols from racemates
Fantin, G
Fogagnolo, M
Giovannini, PP
Medici, A
Pedrini, P
[J]. TETRAHEDRON-ASYMMETRY, 1995, 6 (12) : 3047 - 3053
[3] Microbial reduction of methyl-substituted bicyclo[3.2.0]hept-3-en-6-ones: A screening to homochiral endo- and exo-alcohols
Fantin, G
Fogagnolo, M
Medici, A
Pedrini, P
Marotta, E
Monti, M
Righi, P
[J]. TETRAHEDRON-ASYMMETRY, 1996, 7 (01) : 277 - 282
[4] KINETIC RESOLUTION VIA OXIDATION OF ENDO-BICYCLIC OCTENOLS AND HEPTENOLS WITH BACILLUS-STEAROTHERMOPHILUS
FANTIN, G
FOGAGNOLO, M
MEDICI, A
PEDRINI, P
ROSINI, G
[J]. TETRAHEDRON-ASYMMETRY, 1994, 5 (09) : 1635 - 1638
[5] MICROBIAL OXIDATION WITH BACILLUS-STEAROTHERMOPHILUS - HIGH ENANTIOSELECTIVE RESOLUTION OF 1-HETEROARYL AND 1-ARYL ALCOHOLS
FANTIN, G
FOGAGNOLO, M
MEDICI, A
PEDRINI, P
POLI, S
GARDINI, F
[J]. TETRAHEDRON-ASYMMETRY, 1993, 4 (07) : 1607 - 1612
[6] Anti-Prelog microbial reduction of prochiral carbonyl compounds
Fantin, G
Fogagnolo, M
Giovannini, PP
Medici, A
Pedrini, P
Gardini, F
Lanciotti, R
[J]. TETRAHEDRON, 1996, 52 (10) : 3547 - 3552
[7] Enantiomerically pure 4-methyl- and 1,4-dimethyl-bicyclo[3.2.0]hept-3-en-6-ols and ones by microbial redox
Fantin, G
Fogagnolo, M
Marotta, E
Medici, A
Pedrini, P
Righi, P
[J]. CHEMISTRY LETTERS, 1996, (07) : 511 - 512
[8] KINETIC RESOLUTION OF 1-ARYL-ETHANOLS AND 1-HETEROARYL-ETHANOLS BY OXIDATION WITH BAKERS-YEAST
FANTIN, G
FOGAGNOLO, M
MEDICI, A
PEDRINI, P
POLI, S
SINIGAGLIA, M
[J]. TETRAHEDRON LETTERS, 1993, 34 (05) : 883 - 884
[9] Bacillus stearothermophilus alcohol dehydrogenase: A new catalyst to obtain enantiomerically pure bicyclic octen- and hepten-ols and -ones.
Giovannini, PP
Hanau, S
Rippa, M
Bortolini, O
Fogagnolo, M
Medici, A
[J]. TETRAHEDRON, 1996, 52 (05) : 1669 - 1676
[10] ENANTIOSELECTIVE HYDROLYSIS OF 2-METHYLCYCLOHEXANYL ACETATES WITH THE CULTURED-CELLS OF MARCHANTIA-POLYMORPHA
HIRATA, T
IZUMI, S
AKITA, K
YOSHIDA, H
GOTOH, S
[J]. TETRAHEDRON-ASYMMETRY, 1993, 4 (07) : 1465 - 1466

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