Water as green oxidant: a highly selective conversion of organosilanes to silanols with water

被引：73

作者：

Chauhan, Bhanu P. S. ^{[1
]}

Sarkar, Alok ^{[1
]}

Chauhan, Moni ^{[2
]}

Roka, Abhishek ^{[2
]}

机构：

[1] William Paterson Univ, Dept Chem, Engineered Nonomat Lab, Wayne, NJ 07470 USA

[2] CUNY Queensborough Community Coll, Dept Chem, New York, NY 11364 USA

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2009年 / 23卷 / 10期

关键词：

metal nanoparticles; functional silanols; organosilanes; polysiloxane; functionalization; green catalysis; OXIDATION; ALKENYLSILANOLS; EFFICIENT; DERIVATIVES;

D O I：

10.1002/aoc.1528

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Selective hydrolytic oxidation of organohydrosilanes was achieved with water in the presence of Pt-nanoparticle catalyst. The selectivity of the process was established by NMR analysis. In addition, various Pt-based catalysts were screened to compare the activity and selectivity with Pt-nanoparticles catalysis. The method was equally applicable to hydrosilanes bearing unsaturated functional groups, which led to corresponding silanols under mild reaction conditions without formation of any side products. Pt-nanoparticle catalysis was studied in details using UV-vis, TEM and mercury poisoning experiments during the transformation. Copyright (C) 2009 John Wiley & Sons, Ltd.

引用

页码：385 / 390

页数：6

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