3D Fe3S4 flower-like microspheres: high-yield synthesis via a biomolecule-assisted solution approach, their electrical, magnetic and electrochemical hydrogen storage properties

被引：102

作者：

Cao, Feng ^{[1
,2
]}

Hu, Wen ^{[1
,2
]}

Zhou, Liang ^{[1
,2
]}

Shi, Weidong ^{[1
,2
]}

Song, Shuyan ^{[1
,2
]}

Lei, Yongqian ^{[1
,2
]}

Wang, Song ^{[1
,2
]}

Zhang, Hongjie ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Jilin, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

DALTON TRANSACTIONS | 2009年 / 42期

基金：

中国国家自然科学基金;

关键词：

HYDROTHERMAL SYNTHESIS; IRON-OXIDE; NANOSTRUCTURES; FES2; NANOCRYSTALS; NANOTUBES; SHAPE; NANOPARTICLES; STABILITY; CYSTEINE;

D O I：

10.1039/b912569h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Well-defined 3D Fe3S4 flower-like microspheres were synthesized via a simple biomolecule-assisted hydrothermal process for the first time. On the basis of a series of contrast experiments, the probable growth mechanism and fabrication process of the products were proposed. The electrical conductivity property of the as-synthesized Fe3S4 sample exhibited a rectifying characteristic when a forward bias was applied for the bottom-contacted device. The magnetic properties of the products were studied as well and the results demonstrated that the products presented ferromagnetic properties related to the corresponding microstructure. In addition, we first verified that the Fe3S4 flower-like microspheres could store hydrogen electrochemically, and a discharge capacity of 214 mA h g(-1) was measured without any activation under normal atmospheric conditions at room temperature.

引用

页码：9246 / 9252

页数：7

共 69 条

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