Interaction of hydrogen with accessible metal sites in the metal-organic frameworks M2(dhtp) (CPO-27-M; M = Ni, Co, Mg)

被引：163

作者：

Dietzel, Pascal D. C. ^{[1
]}

Georgiev, Peter A. ^{[2
]}

Eckert, Juergen ^{[3
]}

Blom, Richard ^{[1
]}

Straessle, Thierry ^{[4
,5
]}

Unruh, Tobias ^{[6
]}

机构：

[1] SINTEF Mat & Chem, N-0314 Oslo, Norway

[2] Univ Milan, Dept Struct Chem, I-20133 Milan, Italy

[3] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93016 USA

[4] ETH, Neutron Scattering Lab, CH-5232 Villigen, Switzerland

[5] Paul Scherrer Inst, CH-5232 Villigen, Switzerland

[6] Tech Univ Munich, FRM II, D-84748 Garching, Germany

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 27期

关键词：

ADSORPTION PROPERTIES; STORAGE; H-2; CATENATION; BINDING;

D O I：

10.1039/c0cc00091d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogen molecules adsorbed in the nickel, cobalt, and magnesium analogs of the CPO-27 metal-organic framework at low loadings interact significantly more strongly than those adsorbed successively as a consequence of the strong interaction of hydrogen with the coordinatively unsaturated metal cations in the framework.

引用

收藏

页码：4962 / 4964

页数：3

相关论文

共 27 条

[1] Surface interactions and quantum kinetic molecular sieving for H2 and D2 adsorption on a mixed metal-organic framework material [J].

Chen, Banglin ;

Zhao, Xuebo ;

Putkham, Apipong ;

Hong, Kunlun ;

Lobkovsky, Emil B. ;

Hurtado, Eric J. ;

Fletcher, Ashleigh J. ;

Thomas, K. Mark .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (20) :6411-6423

[2] Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal-organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction [J].

Dietzel, Pascal D. C. ;

Johnsen, Rune E. ;

Fjellvag, Helmer ;

Bordiga, Silvia ;

Groppo, Elena ;

Chavan, Sachin ;

Blom, Richard .

CHEMICAL COMMUNICATIONS, 2008, (41) :5125-5127

[3] Base-induced formation of two magnesium metal-organic framework compounds with a bifunctional tetratopic ligand [J].

Dietzel, Pascal D. C. ;

Blom, Richard ;

Fjellvag, Helmer .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (23) :3624-3632

[4] Structural changes and coordinatively unsaturated metal atoms on dehydration of honeycomb analogous microporous metal-organic frameworks [J].

Dietzel, Pascal D. C. ;

Johnsen, Rune E. ;

Blom, Richard ;

Fjellvag, Helmer .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (08) :2389-2397

[5] Hydrogen adsorption in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework [J].

Dietzel, PDC ;

Panella, B ;

Hirscher, M ;

Blom, R ;

Fjellvåg, H .

CHEMICAL COMMUNICATIONS, 2006, (09) :959-961

[6] An in situ high-temperature single-crystal investigation of a dehydrated metal-organic framework compound and field-induced magnetization of one-dimensional metaloxygen chains [J].

Dietzel, PDC ;

Morita, Y ;

Blom, R ;

Fjellvåg, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (39) :6354-6358

[7] Hydrogen storage in microporous metal-organic frameworks with exposed metal sites [J].

Dinca, Mircea ;

Long, Jeffrey R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (36) :6766-6779

[8] Observation of exceptionally strong binding of molecular hydrogen in a porous material:: Formation of an η2-H2 complex in a Cu-exchanged ZSM-5 zeolite [J].

Georgiev, Peter A. ;

Albinati, Alberto ;

Mojet, Barbara L. ;

Ollivier, Jacques ;

Eckert, Juergen .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (26) :8086-+

[9] Energetics and Dynamics of H2 Adsorbed in a Nanoporous Material at Low Temperature [J].

Kong, Lingzhu ;

Roman-Perez, Guillermo ;

Soler, Jose M. ;

Langreth, David C. .

PHYSICAL REVIEW LETTERS, 2009, 103 (09)

[10] Modeling the Hydrogen Storage Materials with Exposed M2+ Coordination Sites [J].

Kosa, Monica ;

Krack, Matthias ;

Cheetham, Anthony K. ;

Parrinello, Michele .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (42) :16171-16173