STM studies of submonolayer coverages of Ag on Ge(111)

被引:25
作者
Spence, DJ [1 ]
Tear, SP [1 ]
机构
[1] Univ York, Dept Phys, York YO1 5DD, N Yorkshire, England
关键词
adatoms; germanium; low-index single crystal surfaces; metal-semiconductor interfaces; scanning tunnelling microscopy; silver; surface relaxation and reconstruction;
D O I
10.1016/S0039-6028(98)80014-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Submonolayer coverages of Ag on Ge(111) have been studied under ultra-high vacuum using STM. Atomically resolved images of the (root 33 x root 33)R30 degrees reconstruction have been obtained. The images obtained from the 4 x4 structure are strongly dependent upon the bias voltage polarity, indicating a significant influence from electronic effects. A new model is proposed which has the reconstruction occurring within the top bi-layer of an unreconstructed Ge(111) surface. STM images of the (root 33 x root 33)R30 degrees reconstruction show a structure very similar to that obtained for Ag/Si(111), indicating that the surface is a honeycomb-chained-trimer structure. Images have also been obtained of 3 x 1 and 5 x 1 regions and possible models for these structures are proposed. (C) 1998 Elsevier Science B.V.
引用
收藏
页码:91 / 104
页数:14
相关论文
共 53 条
[41]   LOCAL ELECTRON-STATES AND SURFACE GEOMETRY OF SI(111)-(SQUARE-ROOT 3 X SQUARE-ROOT 3)AG [J].
VANLOENEN, EJ ;
DEMUTH, JE ;
TROMP, RM ;
HAMERS, RJ .
PHYSICAL REVIEW LETTERS, 1987, 58 (04) :373-376
[42]   Competing processes and controlling energies at the Ag/Ge(111) interface [J].
Venables, JA ;
Metcalfe, FL ;
Sugawara, A .
SURFACE SCIENCE, 1997, 371 (2-3) :420-430
[43]   THE STRUCTURE OF SI(111)-(SQUARE-ROOT-3X SQUARE-ROOT-3)R30-DEGREES-AG DETERMINED BY SURFACE X-RAY-DIFFRACTION [J].
VLIEG, E ;
VANDERGON, AWD ;
VANDERVEEN, JF ;
MACDONALD, JE ;
NORRIS, C .
SURFACE SCIENCE, 1989, 209 (1-2) :100-114
[44]   STRUCTURE-ANALYSIS OF SI(111)-(SQUARE-ROOT-3 X SQUARE-ROOT-3)R 30-DEGREES/AG USING X-RAY STANDING WAVES [J].
VLIEG, E ;
FONTES, E ;
PATEL, JR .
PHYSICAL REVIEW B, 1991, 43 (09) :7185-7193
[45]   EVIDENCE FOR GERMANIUM SEGREGATION ON THIN-FILMS OF AG ON GE(111) [J].
WACHS, AL ;
MILLER, T ;
CHIANG, TC .
PHYSICAL REVIEW B, 1986, 33 (12) :8870-8873
[46]   SURFACE RECONSTRUCTIONS IN THE AG/SI(111) SYSTEM [J].
WAN, KJ ;
LIN, XF ;
NOGAMI, J .
PHYSICAL REVIEW B, 1993, 47 (20) :13700-13712
[47]   COMPARISON OF THE 3X1 RECONSTRUCTIONS OF THE SI(111) SURFACE INDUCED BY LI AND AG [J].
WAN, KJ ;
LIN, XF ;
NOGAMI, J .
PHYSICAL REVIEW B, 1992, 46 (20) :13635-13638
[48]   REEXAMINATION OF THE AG/SI(111)-ROOT-3 X ROOT-3 SURFACE BY SCANNING TUNNELING MICROSCOPY [J].
WAN, KJ ;
LIN, XF ;
NOGAMI, J .
PHYSICAL REVIEW B, 1992, 45 (16) :9509-9512
[49]   THEORETICAL CALCULATIONS OF THE SCANNING-TUNNELING-MICROSCOPY IMAGES OF THE SI(111)-SQUARE-ROOT-3X-SQUARE-ROOT-3-AG SURFACE [J].
WATANABE, S ;
AONO, M ;
TSUKADA, M .
PHYSICAL REVIEW B, 1991, 44 (15) :8330-8333
[50]   STRUCTURAL MODEL FOR THE METAL-INDUCED SI(111)3X1 RECONSTRUCTION [J].
WEITERING, HH ;
DINARDO, NJ ;
PEREZSANDOZ, R ;
CHEN, J ;
MELE, EJ .
PHYSICAL REVIEW B, 1994, 49 (23) :16837-16840