Growth of highly (100)-oriented Zr-rich PZT thin films on Pt/Ti/SiO2/Si substrates by a simple sol-gel process

被引:21
作者
Fu, XR [1 ]
Li, JH
Song, ZT
Lin, CL
机构
[1] Chinese Acad Sci, Shanghai Inst Met, State Key Lab Funct Mat Informat, Shanghai 200050, Peoples R China
[2] Jiangsu Inst Petrochem Technol, Funct Mat Lab, Changzhou 213016, Peoples R China
基金
中国国家自然科学基金;
关键词
lead zirconate titanate; ferroelectricity; pyroelectric; sol-gel;
D O I
10.1016/S0022-0248(00)00824-1
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Zr-rich lead zirconate titanate thin films with highly preferential (1 0 0) orientation, PZT80/20 and PZT85/15, and randomly oriented PZT70/30 thin films have been successfully prepared on (1 1 1)Pt-coated Si substrates using the sol-gel process with rapid thermal annealing (RTA) at 700 degreesC for 200 s. The results of X-ray diffraction, including rocking curve measurements, suggest that PZT80/20 and PZT85/15 have a single (1 0 0) orientation with the rocking curve FWHM of around 0.5 degrees. The dielectric properties of each film have been measured as well. The results show that highly (1 0 0)-oriented PZT85/15 films exhibit higher remnant polarization (2P(r) = 41.4 mu /cm(2)) and higher coercive field (2E(c) = 111 kV/cm) than randomly oriented PZT70/30 films (2P(r) = 33.4 muC/cm(2) and 2E(c) = 106 kV/cm, respectively). (C) 2000 Published by Elsevier Science B.V.
引用
收藏
页码:82 / 87
页数:6
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